The role of pyruvic acid as starting material in some organic reactions in the presence of SBA-Pr-SO3H nanocatalyst

被引：11

作者：

Ziarani, Ghodsi Mohammadi ^{[1
]}

Gholamzadeh, Parisa ^{[1
]}

Badiei, Alireza ^{[2
]}

Vavsari, Vaezeh Fathi ^{[1
]}

机构：

[1] Alzahra Univ, Dept Chem, Vanak Sq, Tehran, Iran

[2] Univ Tehran, Sch Chem, Coll Sci, Tehran, Iran

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2018年 / 44卷 / 01期

关键词：

Pyruvic acid; SBA-Pr-SO3H; Oxindole; Niementowski reaction; Ugi reaction; ONE-POT SYNTHESIS; MESOPOROUS SILICA; GREEN SYNTHESIS; EFFICIENT SYNTHESIS; DERIVATIVES; CATALYST; ALKALOIDS; SBA-15; QUINAZOLIN-4(3H)-ONES; NANOREACTOR;

D O I：

10.1007/s11164-017-3103-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pyruvic acid contains three different reactive positions: -COOH, ketone carbonyl and methyl groups. Correspondingly, pyruvic acid was applied as starting material in the modified Niementowski reaction and Aldol condensation using SBA-Pr-SO3H as an efficient nanocatalyst. Aldol condensation of pyruvic acid and oxindole provided a new oxindol-based carboxylic acid which was subsequently used in the Ugi four-component reaction. Moreover, through the modified Niementowski reaction of pyruvic acid, new derivatives of quiazoline were produced in the presence of SBA-Pr-SO3H. The obtained products are important due to their potentially biological active skeletons.

引用

页码：277 / 288

页数：12

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