Intermolecular Coulombic decay of clusters

被引:28
|
作者
Santra, R
Zobeley, J
Cederbaum, LS
Tarantelli, F
机构
[1] Heidelberg Univ, Inst Phys Chem, D-69120 Heidelberg, Germany
[2] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy
[3] Univ Perugia, CNR, CISM, I-06123 Perugia, Italy
关键词
clusters; valence ionization; electronic decay;
D O I
10.1016/S0368-2048(00)00256-5
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Following inner-valence ionization of a cluster, the system can relax by ultrafast electron emission. In contrast to Anger decay this novel process is intermolecular. It is characterized by an efficient Coulombic energy transfer mechanism between monomers in the cluster. As an example, we present an analysis of the hydrogen fluoride trimer, based on extensive ab initio computations. (C) 2001 Elsevier Science B.dV. All rights reserved.
引用
收藏
页码:41 / 47
页数:7
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