Homopropargylic alcohols from propargylic derivatives via butyltelluro allene compounds

被引:0
|
作者
Dabdoub, MJ
Rotta, JCG
机构
关键词
telluro allenes; propargyl bromide; propargyl tosylate; homopropargylic alcohols; propargyl tellurides;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Butyltelluro allenes have been prepared efficiently from propargyl bromides or tosylates. Reaction of butyltelluro allenes with butyllithium in THF at -78 degrees C followed by addition of a variety of aldehydes results in formation of homopropargylic alcohols in good yields.
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页码:526 / &
页数:4
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