Di-μ-nitrosyl-bis[(η5-pentamethylcyclo-pentadienyl)ruthenium(0)](Ru-Ru)

被引：5

作者：

Pearsal, Matthew

Gembicky, Milan

Dominiak, Paulina

Larsen, Anna

Coppens, Philip

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

[2] Ithaca Coll, Dept Chem, Ithaca, NY 14850 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807045321

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title structure, [Ru2(C10H15)2(NO)2], consists of the two Ru atoms doubly bridged via the N atoms of the two NO groups, with two penta-methyl-cyclo-penta-dienyl (Cp) rings protruding away from the bridged system on opposite sides. The asymmetric unit contains two independent dimer mol-ecules with an average Ru - Ru distance of 2.538 (7) Å and an average Ru - N - Ru angle of 97.2 (3)°. The compound was obtained as the product of a facile reaction between CpRu(NO)(OSO2CF3)2 and excess neat 2-propanol. The crystals were grown from CH2Cl2 solution at ambient temperature under a nitro-gen atmosphere. © International Union of Crystallography 2007.

引用

页码：M2596 / U1489

页数：22

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