Di-μ-nitrosyl-bis[(η5-pentamethylcyclo-pentadienyl)ruthenium(0)](Ru-Ru)

被引：5
|
作者：
Pearsal, Matthew
Gembicky, Milan
Dominiak, Paulina
Larsen, Anna
Coppens, Philip
机构：
[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA
[2] Ithaca Coll, Dept Chem, Ithaca, NY 14850 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807045321
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title structure, [Ru2(C10H15)2(NO)2], consists of the two Ru atoms doubly bridged via the N atoms of the two NO groups, with two penta-methyl-cyclo-penta-dienyl (Cp) rings protruding away from the bridged system on opposite sides. The asymmetric unit contains two independent dimer mol-ecules with an average Ru - Ru distance of 2.538 (7) Å and an average Ru - N - Ru angle of 97.2 (3)°. The compound was obtained as the product of a facile reaction between CpRu(NO)(OSO2CF3)2 and excess neat 2-propanol. The crystals were grown from CH2Cl2 solution at ambient temperature under a nitro-gen atmosphere. © International Union of Crystallography 2007.
引用
收藏
页码：M2596 / U1489
页数：22
相关论文
共 50 条
  • [1] Di-μ-nitrosyl-bis[(η5-pentamethylcyclopentadienyl)ruthenium(0)](Ru-Ru) (vol E63, pg m2596, 2007)
    Pearsal, Matthew
    Gembicky, Milan
    Dominiak, Paulina
    Larsen, Anna
    Coppens, Philip
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : E25 - E25
  • [2] DI-MU-NITROSYL-TRANS-BIS[BIS(ACETYLACETONATO)RUTHENIUM](RU-RU)
    BOTTOMLEY, F
    WHITE, PS
    MUKAIDA, M
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (OCT): : 2674 - 2676
  • [3] Di-μ-pivalamidato-bis[dicarbonyl(triphenylphosphine)ruthenium(II)](Ru-Ru)
    Auzias, M
    Therrien, B
    Süss-Fink, G
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M2426 - M2427
  • [4] Di-μ-propionato-bis[dicarbonyl(triphenylphosphine)ruthenium(I)](Ru-Ru)
    Gaviño, R
    Pellegrini, S
    Castanet, Y
    Mortreux, A
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M1762 - M1764
  • [5] SYNTHESIS AND STRUCTURE OF DI-μ-ACETATOBIS [DICARBONYLPYRAZOLERUTHENIUM(I)] (Ru-Ru)
    Huang, C. H.
    Lu, T. H.
    Lee, W. M.
    Shiu, K. B.
    [J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1996, 52 : C305 - C305
  • [6] DI-MU-(CARBOXYLATO)-BIS[DICARBONYL(TRI-TERT-BUTYLPHOSPHANE)RUTHENIUM(I)](RU-RU)
    SCHUMANN, H
    OPITZ, J
    [J]. CHEMISCHE BERICHTE-RECUEIL, 1980, 113 (03): : 989 - 994
  • [7] DI-MU-METHOXI-BIS[DICARBONYL(TRI-TERT-BUTYLPHOSPHINE)RUTHENIUM(I)](RU-RU)
    SCHUMANN, H
    OPITZ, J
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1978, 33 (11): : 1338 - 1340
  • [8] SYNTHESIS, PROPERTIES, AND STRUCTURE OF DI-MU-HALOGENO-BIS[DICARBONYL(TRI-TERT-BUTYLPHOSPHANE)-RUTHENIUM(I)](RU-RU)
    SCHUMANN, H
    OPITZ, J
    PICKARDT, J
    [J]. CHEMISCHE BERICHTE-RECUEIL, 1980, 113 (04): : 1385 - 1393
  • [9] DI-MU-IODO-BIS[DICARBONYL(DI-TERT-BUTYLPHOSPHINE)RUTHENIUM(I)](RU-RU) AND BIS(TRI-TERT-BUTYLPHOSPHONIUM)DI-MU-IODO-BIS[CARBONYL-DIIODO(DI-TERT-BUTYLPHOSPHINE)RUTHENIUM(II)]
    SCHUMANN, H
    OPITZ, J
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1980, 35 (01): : 38 - 44
  • [10] PREPARATION, PROPERTIES AND CRYSTAL-STRUCTURE OF DI-MU-(BUTYRATO)-BIS[DICARBONYL(TRI-T-BUTYLPHOSPHINE)RUTHENIUM(I)](RU-RU)
    SCHUMANN, H
    OPITZ, J
    PICKARDT, J
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 128 (02) : 253 - 264
12345