Programmable metal assembly on bio-inspired templates

被引：69
|
作者：
Tanaka, Kentaro [1 ]
Shionoya, Mitsuhiko [2 ]
机构：
[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan
来源：
COORDINATION CHEMISTRY REVIEWS | 2007年 / 251卷 / 21-24期
关键词：
assembled metal complexes; DNA; self-assembly; template synthesis;
D O I：
10.1016/j.ccr.2007.08.018
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Besides the biological importance of DNA as genetic information storage and expression, DNA has great potential to act as a smart molecule for programmable self-assembly of functional units since it is possible to encode molecular assembled systems using sequences of nucleobases in a designable fashion. Recently, we have reported a novel base-pairing motif in DNA duplex that is based on the replacement of hydrogen-bonded base pairs by metal-mediated base pairs. This review covers our recent approaches to precise programming of metal arrays by means of artificial DNA templates. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：2732 / 2742
页数：11
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