Miscibility and specific interactions in blends of poly(vinyl phenyl ketone hydrogenated) with poly(2,6-dimethyl-1,4-phenylene oxide)

被引：6

作者：

Maldonado-Santoyo, M

Nuño-Donlucas, SM

Cesteros, LC

Katime, I

机构：

[1] Univ Guadalajara, Dept Quim, Guadalajara 44430, Jalisco, Mexico

[2] Univ Guadalajara, Dept Ingn Quim, Guadalajara 44430, Jalisco, Mexico

[3] Univ Basque Country, Fac Ciencias, Dept Quim Fis, Grp Neuvos Mat, Bilbao 48990, Spain

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2004年 / 91卷 / 03期

关键词：

poly(vinyl phenyl ketone hydrogenated); poly(2,6-dimethyl-1,4-phenylene oxide); specific interactions; hydrogen bonding; miscibility blend;

D O I：

10.1002/app.13242

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The miscibility behavior of poly(vinyl phenyl ketone hydrogenated) (PVPhKH) and poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) are studied by differential scanning calorimetry, thermomechanical analysis, and FTIR spectroscopy. Two miscibility windows between 10 to 40 and 60 to 90 wt % PPO are detected. Only the blend with 50 wt % PPO is immiscible. The best fit of the Gordon-Taylor equation of the experimental glass-transition temperatures for miscible PVPhKH/PPO blends is shown. A study by FTIR spectroscopy suggests that hydrogen bonding interactions are formed between the hydroxyl groups of PVPhKH and the ether groups of PPO. (C) 2003 Wiley Periodicals, Inc.

引用

页码：1887 / 1892

页数：6

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