Aerobic Oxidation of Cyclic Amines to Lactams Catalyzed by PVP-Stabilized Nanogold

被引：37
|
作者：
Preedasuriyachai, Patcharee [1 ,2 ]
Chavasiri, Warinthorn [3 ]
Sakurai, Hidehiro [1 ,4 ,5 ]
机构：
[1] Grad Univ Adv Studies, Dept Funct Mol Sci, Okazaki, Aichi 4448787, Japan
[2] Chulalongkorn Univ, Fac Sci, Program Petrochem & Polymer Sci, Bangkok 10330, Thailand
[3] Chulalongkorn Univ, Fac Sci, Dept Chem, Bangkok 10330, Thailand
[4] Inst Mol Sci, Res Ctr Mol Scale Nanosci, Okazaki, Aichi 4448787, Japan
[5] Japan Sci & Technol Agcy, PRESTO, Tokyo 1020075, Japan
来源：
SYNLETT | 2011年 / 08期
关键词：
gold nanoclusters; amine; oxidation; amide; GOLD NANOCLUSTERS; INTRAMOLECULAR ADDITION; UNACTIVATED ALKENES; ONE-POT; ALDEHYDES; IMINES; AMIDES; NANOPARTICLES; BENZYLAMINES; AMIDATION;
D O I：
10.1055/s-0030-1259937
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Gold nanoclusters stabilized by poly(N-vinyl-2-pyrrolidone) (Au:PVP) are active and selective catalysts under aerobic conditions for oxidation of cyclic secondary amines at the a-position of the nitrogen atom. The catalyst accelerates the formation of the imines by oxidation of the amines in aqueous solvent to afford the corresponding lactams.
引用
收藏
页码：1121 / 1124
页数：4
相关论文
共 50 条
  • [31] Aerobic Oxidation of Benzyl Amines to Benzyl Imines Catalyzed by Metal-Organic Framework Solids
    Dhakshinamoorthy, Amarajothi
    Alvaro, Mercedes
    Garcia, Hermenegildo
    CHEMCATCHEM, 2010, 2 (11) : 1438 - 1443
  • [32] o-Naphthoquinone-Catalyzed Aerobic Oxidation of Amines to (Ket)imines: A Modular Catalyst Approach
    Goriya, Yogesh
    Kim, Hun Young
    Oh, Kyungsoo
    ORGANIC LETTERS, 2016, 18 (19) : 5174 - 5177
  • [33] Aerobic oxidation of amines to imines catalyzed by a ruthenium complex under solvent-free conditions
    Zhang, Yuecheng
    Lu, Fei
    Huang, Rong
    Zhang, Hongyu
    Zhao, Jiquan
    CATALYSIS COMMUNICATIONS, 2016, 81 : 10 - 13
  • [34] Efficient ruthenium-catalyzed aerobic oxidation of amines by using a biomimetic coupled catalytic system
    Samec, JSM
    Ell, AH
    Bäckvall, JE
    CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (08) : 2327 - 2334
  • [35] Aerobic oxidation of amines to imines catalyzed by bulk gold powder and by alumina-supported gold
    Zhu, Bolin
    Lazar, Mihaela
    Trewyn, Brian G.
    Angelici, Robert J.
    JOURNAL OF CATALYSIS, 2008, 260 (01) : 1 - 6
  • [36] Copper-Catalyzed Aerobic Oxidation of Amines to Imines under Neat Conditions with Low Catalyst Loading
    Patil, Rajendra D.
    Adimurthy, Subbarayappa
    ADVANCED SYNTHESIS & CATALYSIS, 2011, 353 (10) : 1695 - 1700
  • [37] Direct synthesis of nitriles by Cu/DMEDA/TEMPO-catalyzed aerobic oxidation of primary amines with air
    Ma, Xian-Tao
    Xu, Hao
    Xiao, Ying-Lin
    Su, Chen-Liang
    Liu, Jian-Ping
    Xu, Qing
    CHINESE CHEMICAL LETTERS, 2017, 28 (06) : 1336 - 1339
  • [38] Porous Anodic Aluminum Oxide as an Efficient Support for Ruthenium-Catalyzed Aerobic Oxidation of Alcohols and Amines
    Hussain, Muhammad Asif
    Irshad, Mobina
    Ul Haq, Ehsan
    Park, Sungho
    Atif, Muhammad
    Hakeem, Abbas Saeed
    Choi, Bong Gill
    Kim, Jung Won
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2019, 58 (51) : 23025 - 23031
  • [39] Direct synthesis of nitriles by Cu/DMEDA/TEMPO-catalyzed aerobic oxidation of primary amines with air
    Xian-Tao Ma
    Hao Xu
    Ying-Lin Xiao
    Chen-Liang Su
    Jian-Ping Liu
    Qing Xu
    Chinese Chemical Letters, 2017, 28 (06) : 1336 - 1339
  • [40] Activated Carbon Supported Ruthenium Nanoparticles Catalyzed Synthesis of Imines from Aerobic Oxidation of Alcohols with Amines
    Zhang, Yuecheng
    Lu, Fei
    Zhang, Hong-Yu
    Zhao, Jiquan
    CATALYSIS LETTERS, 2017, 147 (01) : 20 - 28
12345