Time-resolved light scattering studies of phase separation in thin film semiconducting polymer blends during spin-coating

被引：77
|
作者：
Jukes, PC
Heriot, SY
Sharp, JS
Jones, RAL [1 ]
机构：
[1] Univ Sheffield, Dept Phys & Astron, Sheffield S3 7RH, S Yorkshire, England
[2] Univ Nottingham, Sch Phys & Astron, Nottingham NG7 2RD, England
来源：
MACROMOLECULES | 2005年 / 38卷 / 06期
关键词：
D O I：
10.1021/ma0477145
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The measurement of the kinetics of film formation and phase separation in a spin-cast polymer blend using in-situ reflectivity and light scattering techniques was discussed. The changes in film thickness during spinning were measured using specular reflectivity. The radially averaged light scattering exhibited pulsations in intensity with a periodicity observed in the specular reflectivity. The secondary phase separation in micrographs of the films after spinning was also elaborated.
引用
收藏
页码：2030 / 2032
页数：3
相关论文
共 50 条
  • [21] TIME-RESOLVED LIGHT-SCATTERING-STUDIES ON KINETICS OF PHASE-SEPARATION AND PHASE DISSOLUTION OF POLYMER BLENDS .4. KINETICS OF PHASE DISSOLUTION OF A BINARY MIXTURE OF POLYSTYRENE AND POLYVINYL METHYL-ETHER)
    KUMAKI, J
    HASHIMOTO, T
    MACROMOLECULES, 1986, 19 (03) : 763 - 768
  • [22] TIME-RESOLVED LIGHT-SCATTERING FROM PHASE SEPARATING POLYMER-SOLUTIONS
    LAGASSE, RR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 195 : 228 - POLY
  • [23] In Situ Imaging and Height Reconstruction of Phase Separation Processes in Polymer Blends during Spin Coating
    Ebbens, Stephen
    Hodgkinson, Richard
    Parnell, Andrew J.
    Dunbar, Alan
    Martin, Simon J.
    Topham, Paul D.
    Clarke, Nigel
    Howse, Jonathan R.
    ACS NANO, 2011, 5 (06) : 5124 - 5131
  • [24] Growth of Long Triisopropylsilylethynyl Pentacene (TIPS-PEN) Nanofibrils in a Polymer Thin Film During Spin-Coating
    Park, Minwoo
    Min, Yuho
    Lee, Yu-Jeong
    Jeong, Unyong
    MACROMOLECULAR RAPID COMMUNICATIONS, 2014, 35 (06) : 655 - 660
  • [25] Direct observation of morphological development during the spin-coating of polystyrenepoly(methyl methacrylate) polymer blends
    Toolan, Daniel T. W.
    ul Haq, Ehtsham
    Dunbar, Alan
    Ebbens, Stephen
    Clarke, Nigel
    Topham, Paul D.
    Howse, Jonathan R.
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2013, 51 (11) : 875 - 881
  • [26] Influence of lateral confinement an phase separation in thin film polymer blends
    Newby, BMZ
    Composto, RJ
    MACROMOLECULES, 2000, 33 (09) : 3274 - 3282
  • [27] Directed phase separation of PFO:PS blends during spin-coating using feedback controlled in situ stroboscopic fluorescence microscopy
    Toolan, Daniel T. W.
    Parnell, Andrew J.
    Topham, Paul D.
    Howse, Jonathan R.
    JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (11) : 3587 - 3592
  • [28] Time-resolved SAXS/WAXS study of phase behavior and crystallization in polymer blends
    Baldrian, J
    Steinhart, M
    Vlcek, P
    Horky, M
    Laggner, P
    Amenitsch, H
    Bernstorff, S
    JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 2002, B41 (4-6): : 1023 - 1032
  • [29] Time-resolved dynamic light scattering studies on gelation process of organic-inorganic polymer hybrids
    Norisuye, T
    Shibayama, M
    Tamaki, R
    Chujo, Y
    MACROMOLECULES, 1999, 32 (05) : 1528 - 1533
  • [30] TIME-RESOLVED, STATIC LIGHT-SCATTERING - NEW POSSIBILITIES IN POLYMER CHARACTERIZATION
    BECKER, A
    SCHMIDT, M
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1991, 50 : 249 - 260
12345