A novel chiral 3D supramolecular framework based on organooxotin cluster

被引:13
|
作者
Li, Shun-Li [1 ]
Ping, Guang-Ju [1 ]
Liu, Jie [1 ]
Ma, Jian-Fang [1 ]
Su, Zhong-Min [1 ]
机构
[1] NE Normal Univ, Dept Chem, Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China
基金
中国国家自然科学基金;
关键词
organotin(IV); cluster; chiral; topology;
D O I
10.1016/j.inoche.2007.11.009
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel triorganotin compound, namely [(Ph3Sn)(3)(CO3)(EtOH)(3)] center dot(nth) center dot Cl center dot H2O (1), exhibits the novel chiral 3D supramolecular structure with a (10,3) topology based on the organooxotin cluster, in which ntb ligand and [(Ph3Sn)(3)(CO3)(EtOH)(3)](+) unit act as three-connected nodes and link each other through O-H center dot center dot center dot N bonds. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:220 / 224
页数:5
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