Natural gas based hydrogen production with zero carbon dioxide emissions

被引：20

作者：

Lopez, Jorge A. Pena ^{[1
]}

Manousiouthakis, Vasilios I. ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biomol Engn, Los Angeles, CA 90095 USA

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2011年 / 36卷 / 20期

基金：

美国国家科学基金会;

关键词：

Hydrogen; Natural gas; Formic acid; Energetically self-sufficient; PRESSURE SWING ADSORPTION; ALTERNATIVE THERMOCHEMICAL CYCLES; HOMOGENEOUS HYDROGENATION; FORMIC-ACID; AQUEOUS-SOLUTION; HEAT; REDUCTION; COMPLEXES; NETWORKS; FUELS;

D O I：

10.1016/j.ijhydene.2011.07.061

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel process flowsheet is presented that co-produces hydrogen and formic acid from natural gas, without emitting any carbon dioxide. The principal technologies employed in the process network include combustion, steam methane reforming (SMR), pressure swing adsorption, and formic acid production from CO(2) and H(2). Thermodynamic analysis provides operating limits for the proposed process, and the use of reaction clusters leads to the synthesis of a feasible process flowsheet. Heat and power integration studies show this flowsheet to be energetically self-sufficient through the use of heat engine and heat pump subnetworks. Operating cost/revenue studies, using current market prices for natural gas, hydrogen and formic acid, identify the proposed design's operating revenue to cost ratio to be 9.29. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：12853 / 12868

页数：16

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