The Tandem Claisen Rearrangement in Organic Synthesis

被引：3

作者：

Zhang, Xueqin ^{[1
]}

Huang, Gangliang ^{[1
]}

Huang, Siqi ^{[1
]}

机构：

[1] Chongqing Normal Univ, Act Carbohydrate Res Ctr, Chongqing 401331, Peoples R China

来源：

CURRENT ORGANIC CHEMISTRY | 2017年 / 21卷 / 27期

关键词：

Tandem Claisen rearrangement; variants; organic synthesis; reaction step; efficiency; application; CYCLIZATION/CLAISEN REARRANGEMENT; ALDER/CLAISEN REARRANGEMENT; CONSTRUCTION; METATHESIS; SEQUENCE; DESYMMETRIZATION; DESIGN; ROUTE; CORE;

D O I：

10.2174/1385272821666170927162859

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Background: Claisen rearrangement is an important reaction, and some "variants" are brought out under the inspiration of Claisen reaction, e.g. Bellus-Claisen rearrangement, Eschenmoser-Claisen rearrangement, Ireland-Claisen rearrangement, and Johnson-Claisen rearrangement. Objective: The application of tandem Claisen rearrangement in organic synthesis was analyzed and discussed herein. Method: We chose some important synthetic studies utilizing the tandem Claisen rearrangement as the key transformation and concisely described and discussed their contents. Results: The tandem reaction could shorten the reaction steps and improve the reaction yield. Conclusion: So, the tandem Claisen rearrangement would greatly improve the efficiency of reaction.

引用

页码：2776 / 2782

页数：7

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