Synthesis and characterization of [Ru(NO)(bpp)Cl • 2H2O] [bpp = N,N′-bis(2-pyridinecarboxamide)-1,3-propane dianion] and [Ru(NO)(bpe)Cl • 2H2O] [bpe = N,N′-bis(2-pyridinecarboxamide)1,2-ethane dianion]

被引:14
|
作者
Fortney, CF [1 ]
Geib, SJ [1 ]
Lin, FT [1 ]
Shepherd, RE [1 ]
机构
[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA
关键词
carboxamido ligands; {RuNO}(6); ruthenium nitrosyl; linear nitrosyl; split NO;
D O I
10.1016/j.ica.2004.09.060
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two ruthenium nitrosyl bis-pyridyl/biscarboxamido compounds, [Ru(NO)(bpp)Cl center dot 2H(2)O] [bpp = N,N'-bis(2-pyridinecarboxamide)-1,3-propane dianion] and [Ru(NO)(bpe)Cl center dot 2H(2)O] [bpe = NN-(bis-2-pyridinecarboxamide)-1,2-ethane dianion] have been characterized by H-1 NMR, C-13{H-1} NMR, and IR spectroscopies, electrospray ionizaton mass spectrometry, and X-ray crystallography. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:2921 / 2932
页数:12
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