Synthesis and characterization of [Ru(NO)(bpp)Cl • 2H2O] [bpp = N,N′-bis(2-pyridinecarboxamide)-1,3-propane dianion] and [Ru(NO)(bpe)Cl • 2H2O] [bpe = N,N′-bis(2-pyridinecarboxamide)1,2-ethane dianion]

被引:14
|
作者
Fortney, CF [1 ]
Geib, SJ [1 ]
Lin, FT [1 ]
Shepherd, RE [1 ]
机构
[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA
关键词
carboxamido ligands; {RuNO}(6); ruthenium nitrosyl; linear nitrosyl; split NO;
D O I
10.1016/j.ica.2004.09.060
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two ruthenium nitrosyl bis-pyridyl/biscarboxamido compounds, [Ru(NO)(bpp)Cl center dot 2H(2)O] [bpp = N,N'-bis(2-pyridinecarboxamide)-1,3-propane dianion] and [Ru(NO)(bpe)Cl center dot 2H(2)O] [bpe = NN-(bis-2-pyridinecarboxamide)-1,2-ethane dianion] have been characterized by H-1 NMR, C-13{H-1} NMR, and IR spectroscopies, electrospray ionizaton mass spectrometry, and X-ray crystallography. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:2921 / 2932
页数:12
相关论文
共 50 条
  • [1] Synthesis and characterization of a new {RuNO}6 complex, [Ru(NO)(bpb)Cl] (bpb = N,N′-bis(2-pyridinecarboxamide)-1,2-benzene dianion)
    Fortney, CF
    Shepherd, RE
    INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (09) : 1065 - 1070
  • [2] Synthesis and study on the interaction of rare earth complexes of N',N-bis(2-pyridinecarboxamide)-1,2-ethane with DNA
    Lu Xiao-hong
    Lin Qiu-yue
    Hu Rui-ding
    Liu Wei-dong
    Feng Jie
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27 (06) : 1176 - 1180
  • [3] Synthesis and study on the interaction of rare earth complexes of N prime ,N-bis (2-pyridinecarboxamide)-1,2-ethane with DNA
    Lu, Xiao-Hong
    Lin, Qiu-Yue
    Hu, Rui-Ding
    Liu, Wei-Dong
    Feng, Jie
    Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis, 2007, 27 (06): : 1176 - 1180
  • [4] Neutral N,N′-bis(2-pyridinecarboxamide)-1,2-ethane as sensing material for determination of lutetium(III) ions in biological and environmental samples
    Ganjali, Mohammad Reza
    Norouzi, Parviz
    Atrian, Alireza
    Faridbod, Farnoush
    Meghdadi, Soraia
    Giahi, Masoud
    MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2009, 29 (01): : 205 - 210
  • [5] Epoxidation with manganese N,N′-bis(2-pyridinecarboxamide) complexes encapsulated in zeolite Y
    Knops-Gerrits, PP
    L'abbe, M
    Jacobs, PA
    HETEROGENEOUS CATALYSIS AND FINE CHEMICALS IV, 1997, 108 : 445 - 452
  • [6] Synthesis, characterization and luminescence properties of N,N'-bis(2-pyridinecarboxamide-1-N-oxide)-1,2-ethane and corresponding lanthanide(III) complexes
    Zhang, Hai-Jun
    Li, Gang
    Yan, Lan
    Yang, Ru-Dong
    JOURNAL OF LUMINESCENCE, 2007, 127 (02) : 316 - 320
  • [7] H-1 and C-13 NMR study of N-(3-pyridinyl)-2-pyridinecarboxamide and N,N'-bis(2-pyridinyl)-1,3-benzenedicarboxamide
    Singha, NC
    Anand, J
    Sathyanarayana, DN
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1997, 53 (09) : 1459 - 1462
  • [8] A novel Ho(III) sensor based on N,N'-bis(2-pyridinecarboxamide)-1,2-benzene as a neutral ion carrier
    Ganjali, Mohammad Reza
    Rasoolipour, Solmaz
    Rezapour, Morteza
    Norouzi, Parviz
    Amirnasr, Mehdi
    Meghdadi, Soraia
    JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2006, 17 (07) : 1211 - 1216
  • [9] Alkane partial oxidation with iron N,N'-bis(2-pyridinecarboxamide) complexes encaged in zeolite Y
    KnopsGerrits, PP
    Labbe, M
    Leung, WH
    VanBavel, AM
    Langouche, G
    Bruynseraede, I
    Jacobs, PA
    11TH INTERNATIONAL CONGRESS ON CATALYSIS - 40TH ANNIVERSARY, PTS A AND B, 1996, 101 : 811 - 820
  • [10] {[Co(μ-bpe)(bpe)2(H2O)2](0.5bpe)(H2O)(ClO4)2}n:: a transition metal-organo network with a novel supramolecular architecture (bpe = 1,2-bis(4-pyridyl)ethane)
    Ferbinteanu, M
    Marinescu, G
    Roesky, HW
    Noltemeyer, M
    Schmidt, HG
    Andruh, M
    POLYHEDRON, 1998, 18 (1-2) : 243 - 248