Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides

被引：30
|
作者：
Bassat, JM
Petitjean, M
Fouletier, J
Lalanne, C
Caboche, G
Mauvy, F
Grenier, JC
机构：
[1] CNRS, ICMCB, F-33608 Pessac, France
[2] Univ Bourgogne, CNRS, LRRS, UMR 5613, F-21078 Dijon, France
[3] INP Grenoble, ENSEEG, LEPMI, F-38402 St Martin Dheres, France
来源：
APPLIED CATALYSIS A-GENERAL | 2005年 / 289卷 / 01期
关键词：
SOFC; mixed conducting oxides; oxygen transport properties; oxygen reduction;
D O I：
10.1016/j.apcata.2005.04.054
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The (18)O/(16)O isotope exchange depth profile technique (IEDP) followed by SIMS characterizations was applied to dense membranes of pure ionic conductors and mixed ionic/electronic conducting materials. It is a very useful tool since we obtain in both cases data concerning the oxygen diffusion in the bulk and the oxygen exchange at the surface of the materials. Comparisons were done, including results concerning the role of the surface with regards to the oxygen reduction reaction. Detailed experimental and analytical processes are given. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：84 / 89
页数：6
相关论文
共 50 条
  • [31] Oxygen surface exchange kinetics of SrTi1-xFexO3-δ mixed conducting oxides
    Yoo, Chung-Yul
    Bouwmeester, Henny J. M.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (33) : 11759 - 11765
  • [32] Oxygen diffusion and surface exchange in the mixed conducting oxides SrTi1-yFeyO3-δ
    Metlenko, Veronika
    Jung, WooChul
    Bishop, Sean R.
    Tuller, Harry L.
    De Souza, Roger A.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (42) : 29495 - 29505
  • [33] DESORPTION AND ISOTOPIC EXCHANGE OF OXYGEN AT A SILVER SURFACE
    SANDLER, YL
    DURIGON, DD
    JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (12): : 4201 - &
  • [34] Oxygen isotopic exchange in animal-respiration
    Day, JNE
    Sheel, P
    NATURE, 1938, 142 : 917 - 917
  • [35] OXYGEN ISOTOPIC EXCHANGE AT AN IGNEOUS INTRUSIVE CONTACT
    NAGY, KL
    PARMENTIER, EM
    EARTH AND PLANETARY SCIENCE LETTERS, 1982, 59 (01) : 1 - 10
  • [36] DETERMINATION OF OXYGEN IN METALS AND METAL OXIDES BY THE ISOTOPIC METHOD
    KIRSHENBAUM, AD
    GROSSE, AV
    TRANSACTIONS OF THE AMERICAN SOCIETY FOR METALS, 1953, 45 : 758 - 770
  • [37] Oxygen exchange and transport in electronically conducting cobaltates
    Diethelm, S
    Closset, A
    Van herle, J
    McEvoy, AJ
    Nisancioglu, K
    5TH EUROPEAN SYMPOSIUM ON ELECTROCHEMICAL ENGINEERING, 1999, (145): : 121 - 128
  • [38] ISOTOPIC EXCHANGE OF MOLECULAR-OXYGEN WITH OXYGEN OF V2O5 MODIFIED WITH OXIDES OF ALKALINE-EARTH METALS
    MINACHEV, KM
    ANTOSHIN, GV
    KLISSURSKI, DG
    GUIN, NK
    ABADZHIJEVA, NT
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1979, 75 : 691 - 694
  • [39] Oxygen exchange with water alters the oxygen isotopic signature of nitrate in soil ecosystems
    Kool, Dorien M.
    Wrage, Nicole
    Oenema, Oene
    Van Kessel, Chris
    Van Groenigen, Jan Willem
    SOIL BIOLOGY & BIOCHEMISTRY, 2011, 43 (06): : 1180 - 1185
  • [40] ISOTOPIC-EXCHANGE OF OXYGEN-18 WITH OXYGEN OF NIOBIUM (V) OXIDE
    ROSS, RA
    KLISSURS.DG
    GRIFFITH, TJ
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1973, 86 (1-2): : 50 - 58
12345