Synthesis and binding properties of new tripodal hexadentate ligands having three quinolinol moieties for trivalent metal cations

被引：19
|
作者：
Hayashi, M [1 ]
Ishii, M [1 ]
Hiratani, K [1 ]
Saigo, K [1 ]
机构：
[1] Univ Tokyo, Grad Sch Engn, Dept Chem & Biochem, Bunkyo Ku, Tokyo 1138656, Japan
来源：
TETRAHEDRON LETTERS | 1998年 / 39卷 / 34期
关键词：
host compounds; ionophores; rearrangement; gallium and compounds;
D O I：
10.1016/S0040-4039(98)01277-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Tripodal hexadentate ligands, having three 8-hydroxyquinolyl or 2-methyl-8-hydroxyquinolyl groups as binding sites, were successfully prepared from the corresponding tris(isobutenyl 8-quinolyl ether) via the Claisen rearrangement. The 2-methyl-8-hydroxyquinolyl derivative exhibited binding ability for several kinds of trivalent metal cations to form 1:1 complexes, and showed selective extractability for Ga3+ among trivalent cations of Group 13 elements. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：6215 / 6218
页数：4
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