New macrocyclic ligands having discrete metal binding sites

被引：62

作者：

Shimakoshi, H ^{[1
]}

Takemoto, H ^{[1
]}

Aritome, I ^{[1
]}

Hisaeda, Y ^{[1
]}

机构：

[1] Kyushu Univ, Dept Chem & Biochem, Grad Sch Engn, Higashi Ku, Fukuoka 8128581, Japan

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 27期

关键词：

macrocyclic ligand; Schiff-base; cobalt complex; X-ray crystallography; redox behavior;

D O I：

10.1016/S0040-4039(02)00923-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New macrocyclic dinucleating ligands have been easily synthesized by Schiff-base condensation reaction with the appropriate aldehyde and amine using the boric ion template method. The ligands hake two N2O2 metal-binding sites which are doubly linked to each other with methylene spacers. The ligands chelate with Co2-, Cu2+ and Ni2+ to form dimetallic Compounds in high yields. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：4809 / 4812

页数：4

共 50 条

[1] Anion binding by macrocyclic ligands and their metal complexes
Martell, AE
Lu, Q
Nation, DA
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 56 - IEC
[2] Phosphate anion binding by macrocyclic dinucleating ligands and their metal complexes
Department of Chemistry, Texas A and M University, College Station, TX 77842-3012, United States
Polyhedron, 25 (3203-3218):
[3] Phosphate anion binding by macrocyclic dinucleating ligands and their metal complexes
Martell, AE
Motekaitis, RJ
Lu, Q
Nation, DA
POLYHEDRON, 1999, 18 (25) : 3203 - 3218
[4] NEW MACROCYCLIC POLYETHERS WITH REMOTE BINDING-SITES
REBEK, J
WATTLEY, RV
JOURNAL OF HETEROCYCLIC CHEMISTRY, 1980, 17 (04) : 749 - 751
[5] TRANSITION METAL COMPLEXES OF NEW SYNTHETIC MACROCYCLIC LIGANDS
BUSCH, DH
HELVETICA CHIMICA ACTA, 1967, : 174 - &
[6] SPECIFICATION OF THE BONDING CAVITIES AVAILABLE IN METAL-BINDING SITES - A COMPARATIVE-STUDY OF A SERIES OF QUADRIDENTATE MACROCYCLIC LIGANDS
HENRICK, K
LINDOY, LF
MCPARTLIN, M
TASKER, PA
WOOD, MP
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (06) : 1641 - 1645
[7] Synthesis of new ligands having O, N and S sites
Saxena, Jyoti
ORIENTAL JOURNAL OF CHEMISTRY, 2008, 24 (01) : 361 - 363
[8] Metal complexes of macrocyclic ligands
Kaden, TA
CHIMIA, 1999, 53 (05) : 208 - 210
[9] TRANSITION METAL COMPLEXES OF A SERIES OF NEW MACROCYCLIC SEXADENTATE LIGANDS
FLEISCHER, EB
TASKER, PA
INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1970, 6 (03): : 349 - +
[10] Ruthenium(II) complexes of some new polynucleating ligands incorporating terpyridyl and macrocyclic aza-crown binding sites
Whittle, B
Batten, SR
Jeffery, JC
Rees, LH
Ward, MD
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (22): : 4249 - 4255

← 1 2 3 4 5 →