Thermodynamic modeling of the Pd-Sb system

被引：3
|
作者：
Han, Wei [1 ]
Li, Mei [1 ]
机构：
[1] Harbin Engn Univ, Key Lab Superlight Mat & Surface Technol, Minist Educ, Coll Mat Sci & Chem Engn, Harbin 150001, Peoples R China
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2010年 / 507卷 / 02期
关键词：
Pd-Sb phase diagram; Thermodynamic modeling; CALPHAD technique; REGULAR SOLUTION MODEL; CRYSTAL-STRUCTURE; ALLOYS; PHASES; PALLADIUM; ELEMENTS; GASB; NI;
D O I：
10.1016/j.jallcom.2010.07.220
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Pd-Sb binary system has been thermodynamically assessed by means of CALPHAD approach. The Redlich-Kister polynomial was used to describe the solution phases, liquid (L) and fcc. The non-stoichiometric compound Pd3Sb and Pd5Sb3 were described by a two-sublattice model (Pd,Sb)(3)Sb and (Pd,Sb)(5)(Pd,Sb)(3). The six intermetallic compounds, Pd8Sb3, Pd20Sb7, Pd5Sb2, Pd2Sb, PdSb and PdSb2, were treated as stoichiometric phases. The parameters of the Gibbs energy expressions were optimized according to all the available experimental information of both the equilibrium data and the thermodynamic results. A set of self-consistent thermodynamic parameters of the Pd-Sb system has been obtained. The calculations agree well with the respective experimental data. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：521 / 525
页数：5
相关论文
共 50 条
  • [21] Thermodynamic modeling of the Pd-Sm system
    Du, ZM
    Yang, HF
    ZEITSCHRIFT FUR METALLKUNDE, 2000, 91 (06): : 455 - 459
  • [22] Thermodynamic modeling of the Au-In-Sb ternary system
    H. S. Liu
    C. L. Liu
    C. Wang
    Z. P. Jin
    K. Ishida
    Journal of Electronic Materials, 2003, 32 : 81 - 88
  • [23] A Thermodynamic Modeling of the Fe-Nd-Sb System
    Wang, Wei
    Liu, Tingan
    Song, Huilei
    Xue, Songyi
    Zhang, Wanyou
    Zhang, Haifeng
    Zhang, Lanhe
    Jia, Yanping
    Wang, Nan
    Cheng, Xin
    Zeng, Chunhui
    MATERIALS TRANSACTIONS, 2016, 57 (02) : 103 - 111
  • [24] Thermodynamic modeling of the Ga-Pt-Sb system
    Guo, Cuiping
    Li, Changrong
    Du, Zhenmin
    CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2016, 52 : 169 - 179
  • [25] Thermodynamic Modeling of the Cu-Sb-Se System
    Liu, Runlin
    Wang, Jiong
    Cui, Dongyu
    JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION, 2023, 44 (06) : 687 - 703
  • [26] Thermodynamic Modeling of the Cu-Sb-Se System
    Runlin Liu
    Jiong Wang
    Dongyu Cui
    Journal of Phase Equilibria and Diffusion, 2023, 44 : 687 - 703
  • [27] Thermodynamic Modeling of the Ag-Sb-Sn System
    Lysenko, V. A.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2020, 94 (09) : 1747 - 1755
  • [28] Thermodynamic modeling of the Mg-Al-Sb system
    Balakumar, T
    Medraj, M
    CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2005, 29 (01): : 24 - 36
  • [29] Thermodynamic modeling of the Au-In-Sb ternary system
    Liu, HS
    Liu, CL
    Wang, C
    Jin, ZP
    Ishida, K
    JOURNAL OF ELECTRONIC MATERIALS, 2003, 32 (02) : 81 - 88
  • [30] Plasmonic Pd-Sb nanosheets for photothermal CH4 conversion to HCHO and therapy
    Wang, Mengjun
    Jia, Jun
    Meng, Zhaodong
    Xia, Jing
    Hu, Xinyan
    Xue, Fei
    Peng, Huiping
    Meng, Xiangmin
    Yi, Jun
    Chen, Xiaolan
    Li, Jun
    Guo, Yuzheng
    Xu, Yong
    Huang, Xiaoqing
    SCIENCE ADVANCES, 2024, 10 (36):
12345