Thermodynamic modeling of the Pd-Sb system

被引：3

作者：

Han, Wei ^{[1
]}

Li, Mei ^{[1
]}

机构：

[1] Harbin Engn Univ, Key Lab Superlight Mat & Surface Technol, Minist Educ, Coll Mat Sci & Chem Engn, Harbin 150001, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2010年 / 507卷 / 02期

关键词：

Pd-Sb phase diagram; Thermodynamic modeling; CALPHAD technique; REGULAR SOLUTION MODEL; CRYSTAL-STRUCTURE; ALLOYS; PHASES; PALLADIUM; ELEMENTS; GASB; NI;

D O I：

10.1016/j.jallcom.2010.07.220

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Pd-Sb binary system has been thermodynamically assessed by means of CALPHAD approach. The Redlich-Kister polynomial was used to describe the solution phases, liquid (L) and fcc. The non-stoichiometric compound Pd3Sb and Pd5Sb3 were described by a two-sublattice model (Pd,Sb)(3)Sb and (Pd,Sb)(5)(Pd,Sb)(3). The six intermetallic compounds, Pd8Sb3, Pd20Sb7, Pd5Sb2, Pd2Sb, PdSb and PdSb2, were treated as stoichiometric phases. The parameters of the Gibbs energy expressions were optimized according to all the available experimental information of both the equilibrium data and the thermodynamic results. A set of self-consistent thermodynamic parameters of the Pd-Sb system has been obtained. The calculations agree well with the respective experimental data. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：521 / 525

页数：5

共 50 条

[1] CRYSTAL-STRUCTURE OF THE RHOMBOHEDRAL PHASE IN THE PD-SB SYSTEM
MAN, LI
IMAMOV, RM
KRISTALLOGRAFIYA, 1979, 24 (03): : 632 - 635
[2] BINARY-SYSTEMS PD-SB AND PT-SB
DURUSSEL, P
FESCHOTTE, P
JOURNAL OF ALLOYS AND COMPOUNDS, 1991, 176 (01) : 173 - 181
[3] ISOMER SHIFTS AND ELECTRONIC STRUCTURE OF PD-SB ALLOYS
MONTGOMERY, H
RUBY, SL
PHYSICAL REVIEW B-SOLID STATE, 1970, 1 (12): : 4529 - +
[4] THERMODYNAMIC PROPERTIES OF SOLID PALLADIUM-RICH PD-CD, PD-IN, PD-SN AND PD-SB ALLOYS
DARBY, JB
MYLES, KM
PRATT, JN
ACTA METALLURGICA, 1971, 19 (01): : 7 - &
[5] Thermodynamics of hydrogen absorption by Pd-Sb and Pd-Bi alloys
Nagasaki Univ, Nagasaki, Japan
Int J Hydrogen Energy, 11-12 (1009-1015):
[6] Thermodynamics of hydrogen absorption by Pd-Sb and Pd-Bi alloys
Sakamoto, Y
Ura, M
Hisamoto, T
Flanagan, TB
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1996, 21 (11-12) : 1009 - 1015
[7] Pd-Sb Rhombohedra with an Unconventional Rhombohedral Phase as a Trifunctional Electrocatalyst
Xu, Bingyan
Liu, Tianyang
Liang, Xiaocong
Dou, Wenjie
Geng, Hongbo
Yu, Zhiyang
Li, Yafei
Zhang, Ying
Shao, Qi
Fan, Jingmin
Huang, Xiaoqing
ADVANCED MATERIALS, 2022, 34 (50)
[8] Thermodynamic Modeling of the Ag–Sb–Sn System
V. A. Lysenko
Russian Journal of Physical Chemistry A, 2020, 94 : 1747 - 1755
[9] Thermodynamic modeling of the In-Pt-Sb system
Guo, Cuiping
Li, Changrong
Shang, Shunli
Du, Zhenmin
INTERNATIONAL JOURNAL OF MATERIALS RESEARCH, 2014, 105 (06) : 525 - 536
[10] MAGNETIC SUSCEPTIBILITIES OF PD-CD PD-SB AND PT-CU BINARY ALLOYS
LAM, DJ
MYLES, KM
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1966, 21 (08) : 1503 - &

← 1 2 3 4 5 →