Regiochemical control of the catalytic asymmetric hydroboration of 1,2-diarylalkenes

被引：35
|
作者：
Black, A [1 ]
Brown, JM [1 ]
Pichon, C [1 ]
机构：
[1] Chem Res Lab, Oxford OX1 3TA, England
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 42期
关键词：
D O I：
10.1039/b508292g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hydroboration of stilbenes and related disubstituted alkenes catalysed by QUINAP complexes may proceed with high enantio- and regioselectivity; rhodium and iridium catalysts give the same product regioisomer but opposite enantiomers.
引用
收藏
页码：5284 / 5286
页数：3
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