Miniemulsion reversible addition fragmentation chain transfer polymerization of vinyl acetate

被引：54
|
作者：
Russum, JP [1 ]
Barbre, ND [1 ]
Jones, CW [1 ]
Schork, FJ [1 ]
机构：
[1] Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2005年 / 43卷 / 10期
关键词：
initiators; living polymerization; miniemulsion; poly(vinyl acetate); reversible addition-fragmentation chain transfer (RAFT);
D O I：
10.1002/pola.20681
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly(vinyl acetate) was produced in a controlled manner using RAFT chemistry in a miniemulsion system. Homogeneous nucleation of the vinyl acetate monomer was suppressed through the use of an oil soluble initiator, 2,2'azo-bis(isobutyronitrile). The miniemulsion polymerizations exhibited lower reaction rates than a bulk polymerization.
引用
收藏
页码：2188 / +
页数：7
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