Miniemulsion reversible addition fragmentation chain transfer polymerization of vinyl acetate

被引：54
|
作者：
Russum, JP [1 ]
Barbre, ND [1 ]
Jones, CW [1 ]
Schork, FJ [1 ]
机构：
[1] Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2005年 / 43卷 / 10期
关键词：
initiators; living polymerization; miniemulsion; poly(vinyl acetate); reversible addition-fragmentation chain transfer (RAFT);
D O I：
10.1002/pola.20681
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly(vinyl acetate) was produced in a controlled manner using RAFT chemistry in a miniemulsion system. Homogeneous nucleation of the vinyl acetate monomer was suppressed through the use of an oil soluble initiator, 2,2'azo-bis(isobutyronitrile). The miniemulsion polymerizations exhibited lower reaction rates than a bulk polymerization.
引用
收藏
页码：2188 / +
页数：7
相关论文
共 50 条
  • [1] The reversible addition-fragmentation chain transfer (RAFT) miniemulsion polymerization of vinyl acetate mediated by xanthate
    Jiang, Bo
    Zhang, Qing Hua
    Zhan, Xiao Li
    Chen, Feng Qiu
    [J]. CHINESE CHEMICAL LETTERS, 2009, 20 (06) : 733 - 737
  • [2] The reversible addition-fragmentation chain transfer(RAFT) miniemulsion polymerization of vinyl acetate mediated by xanthate
    Bo Jiang
    [J]. Chinese Chemical Letters, 2009, 20 (06) : 733 - 737
  • [3] Reversible Addition-Fragmentation Chain Transfer Polymerization of Vinyl Acetate Under High Pressure
    Chen, Jing
    Zhao, Xiaoning
    Zhang, Lifen
    Cheng, Zhenping
    Zhu, Xiulin
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2015, 53 (12) : 1430 - 1436
  • [4] Reversible addition-fragmentation chain transfer (RAFT) polymerization of vinyl acetate using xanthates
    Shipp, DA
    Vercoe, K
    Zhang, TX
    Thopasridharan, M
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U4125 - U4126
  • [5] Reversible Addition-Fragmentation Chain Transfer Polymerization of Vinyl Acetate in Bulk and Suspension Systems
    Oliveira, Marco
    Barbosa, Bernardo S.
    Nele, Marcio
    Pinto, Jose Carlos
    [J]. MACROMOLECULAR REACTION ENGINEERING, 2014, 8 (06) : 493 - 502
  • [6] Reversible addition-fragmentation chain transfer polymerization of vinyl acetate and vinyl pivalate in supercritical carbon dioxide
    Pham, Quang Long
    Haldorai, Yuvaraj
    Van Hoa Nguyen
    Kang, ChanKyu
    Shim, Jae-Jin
    [J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2014, 31 (11) : 2101 - 2107
  • [7] Reversible addition-fragmentation chain transfer polymerization of vinyl acetate and vinyl pivalate in supercritical carbon dioxide
    Quang Long Pham
    Yuvaraj Haldorai
    Van Hoa Nguyen
    ChanKyu Kang
    Jae-Jin Shim
    [J]. Korean Journal of Chemical Engineering, 2014, 31 : 2101 - 2107
  • [8] Controlled radical polymerization of styrene in miniemulsion polymerization using reversible addition fragmentation chain transfer
    Uzulina, I
    Gaillard, N
    Guyot, A
    Claverie, K
    [J]. COMPTES RENDUS CHIMIE, 2003, 6 (11-12) : 1375 - 1384
  • [9] Reversible Addition-Fragmentation Chain Transfer Polymerization of Vinyl Chloride
    Abreu, Carlos M. R.
    Mendonca, Patricia V.
    Serra, Armenio C.
    Coelho, Jorge F. J.
    Popov, Anatoliy V.
    Gryn'ova, Ganna
    Coote, Michelle L.
    Guliashvili, Tamaz
    [J]. MACROMOLECULES, 2012, 45 (05) : 2200 - 2208
  • [10] Pseudoliving Polymerization of Vinyl Acetate Mediated by Reversible Addition-Fragmentation Chain-Transfer Agents
    Chernikova, E. V.
    Yulusov, V. V.
    Mineeva, K. O.
    Golubev, V. B.
    Garina, E. S.
    [J]. POLYMER SCIENCE SERIES B, 2011, 53 (7-8) : 437 - 447
12345