Domestic wastewater treatment in a tubular microbial electrolysis cell with a membrane electrode assembly

被引:26
|
作者
Jwa, Eunjin [1 ]
Yun, Yeo-Myeong [2 ]
Kim, Hanki [1 ]
Jeong, Namjo [1 ]
Park, Soon-Chul [1 ]
Nam, Joo-Youn [1 ]
机构
[1] Korea Inst Energy Res, Jeju Global Res Ctr, 200 Haemajihaean Ro, Jeju 63359, South Korea
[2] Chungbuk Natl Univ, Dept Environm Engn, 1 Chungdae Ro, Cheongju 28644, South Korea
关键词
Microbial electrolysis cell; Hydrogen production; Membrane electrode assembly; Domestic wastewater; Seawater; HYDROGEN-PRODUCTION; FUEL-CELLS; POWER-GENERATION; ELECTRICITY-GENERATION; INTERNAL RESISTANCE; CATHODE CATALYST; PERFORMANCE; MEC; CATHOLYTE; ANODES;
D O I
10.1016/j.ijhydene.2018.11.036
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High hydrogen production rate and energy recovery were accomplished in a tubular microbial electrolysis cell (MEC) equipped with a robust membrane electrode assembly (MEA). The current and the hydrogen production of non-flexible MEAs, simply fabricated by directly brushing a catalyst on a self-supporting tubular membrane, were compared with those of a typical MEA, where a cathode is physically combined with a membrane. Current of 34 +/- 2 mA (1.79 +/- 0.05 A/m(2)) and coulombic efficiency of 98.5 +/- 1.0% were achieved in non-flexible MEAs, outperforming the typical MEA under fed-batch mode. The MEA, having a durable coating layer, also showed an enhanced hydrogen production rate and electric energy recovery with values of 0.18 +/- 0.03 m(3)/m(3)-d and 151.9 +/- 1.0%, respectively, even for low strength domestic wastewater (dWW) treatment in the continuous-flow mode. These outcomes were similarly maintained in the case of using seawater, which is a good candidate for an economical and environmentally suitable catholyte. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:652 / 660
页数:9
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