Support effects on the oxidation of methanol at platinum nanoparticles

被引：27
|
作者：
Moghaddam, Reza B. [1 ]
Pickup, Peter G. [1 ]
机构：
[1] Mem Univ Newfoundland, Dept Chem, St John, NF A1B 3X7, Canada
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 2011年 / 13卷 / 07期
基金：
加拿大自然科学与工程研究理事会;
关键词：
Electrocatalysis; Methanol; Platinum; Nanoparticle; Support; ELECTROCATALYTIC OXIDATION; GOLD NANOPARTICLES; POLYANILINE; RUTHENIUM;
D O I：
10.1016/j.elecom.2011.04.015
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The effects of Ru oxide and polyaniline supports on methanol oxidation have been investigated by drop coating of Pt nanoparticles onto glassy carbon electrodes coated with these materials. A thin Ru oxide film, deposited by the spontaneous reaction of Ru(VII) with the carbon surface, has been shown to exert a substantial effect, while the effects of polyaniline were insignificant. The influence of Ru oxide is attributed to the well-known bifunctional mechanism, while previous reports of enhanced methanol oxidation at polyaniline supported Pt catalysts are attributed to better Pt dispersion and/or enhanced transport properties of the catalysts. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：704 / 706
页数：3
相关论文
共 50 条
  • [41] Electrocatalytic oxidation of methanol on platinum nanoparticles electrodeposited onto porous carbon substrates
    F. GLOAGUEN
    J.-M. LE´GER
    C. LAMY
    Journal of Applied Electrochemistry, 1997, 27 : 1052 - 1060
  • [42] Polyaniline hollow tubes loading tiny platinum nanoparticles for boosting methanol oxidation
    Jin, Wen
    Huang, Xinhua
    Cheng, Haiyan
    Xu, Ting
    Wang, Feng
    Guo, Xiaoyu
    Wu, Yiping
    Ying, Ye
    Wen, Ying
    Yang, Haifeng
    APPLIED SURFACE SCIENCE, 2019, 483 : 489 - 495
  • [43] Electrocatalytic oxidation of methanol on platinum nanoparticles electrodeposited onto porous carbon substrates
    Gloaguen, F
    Leger, JM
    Lamy, C
    JOURNAL OF APPLIED ELECTROCHEMISTRY, 1997, 27 (09) : 1052 - 1060
  • [44] Platinum nanoparticles supported on zirconia–carbon black nanocomposites for methanol oxidation reaction
    Cheng-Lan Lin
    Yu-Chi Yeh
    Research on Chemical Intermediates, 2014, 40 : 2207 - 2215
  • [45] Electrocatalytic oxidation of methanol and ethanol at carbon ceramic electrode modified with platinum nanoparticles
    Razmi, H.
    Habibi, Es.
    Heidari, H.
    ELECTROCHIMICA ACTA, 2008, 53 (28) : 8178 - 8185
  • [46] Promoting the methanol oxidation catalytic activity by introducing surface nickel on platinum nanoparticles
    Lu, Siqi
    Li, Huiming
    Sun, Jingyao
    Zhuang, Zhongbin
    NANO RESEARCH, 2018, 11 (04) : 2058 - 2068
  • [47] Influence of nanostructured ceria support on platinum nanoparticles for methanol electrooxidation in alkaline media
    Zhou, Yunyun
    Menendez, Christian L.
    Guinel, Maxime J. -F.
    Needels, Elizabeth C.
    Gonzalez-Gonzalez, Ileana
    Jackson, Dichele L.
    Lawrence, Neil J.
    Cabrera, Carlos R.
    Cheung, Chin Li
    RSC ADVANCES, 2014, 4 (03): : 1270 - 1275
  • [48] Effects of the PdO nanoflake support on electrocatalytic activity of Pt nanoparticles toward methanol oxidation in acidic solutions
    Chen, Chung-Shou
    Pan, Fu-Ming
    JOURNAL OF POWER SOURCES, 2012, 208 : 9 - 17
  • [49] 4A Zeolite Support for Pt Nanoparticles towards Methanol Oxidation
    Cai, Nan
    Wu, Jialu
    Jin, Changchun
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2019, 166 (10) : H387 - H391
  • [50] Structural effects and reactivity in methanol oxidation on polycrystalline and single crystal platinum
    Xia, XH
    Iwasita, T
    Ge, F
    Vielstich, W
    ELECTROCHIMICA ACTA, 1996, 41 (05) : 711 - 718
12345