Synthesis and characterization of single crystals of the layered copper hydroxide acetate Cu2(OH)3(CH3COO)•H2O

被引：42
|
作者：
Svarcova, S. [1 ,2 ]
Klementova, M. [3 ]
Bezdicka, P. [1 ,2 ]
Lasocha, W. [4 ]
Dusek, M. [3 ]
Hradil, D. [1 ,2 ]
机构：
[1] Inst Inorgan Chem AS CR, Vvi, ALMA Lab, Husinec Rez 25068, Czech Republic
[2] Acad Fine Arts Prague, ALMA Lab, Prague 17022 7, Czech Republic
[3] Inst Phys AS CR, Vvi, Prague 18221 8, Czech Republic
[4] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland
来源：
CRYSTAL RESEARCH AND TECHNOLOGY | 2011年 / 46卷 / 10期
关键词：
copper hydroxide acetate; crystal structure; single crystal; pseudomorphous copper oxide; MAGNETIC-PROPERTIES; DOT H2O; ABSORPTION; PROGRAM;
D O I：
10.1002/crat.201100262
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Single-crystals of the layered copper hydroxide acetate Cu-2(OH)(3)(CH3COO)center dot H2O were synthesized by heating copper acetate solution at 60 degrees C. The standard synthesis of the title compound based on slow titration of copper acetate solution with NaOH yielded materials with worse morphology and an additional phase present. The obtained products were characterized with powder X-ray diffraction, high temperature powder X-ray diffraction, scanning electron microscopy and infrared spectroscopy. The crystal structure was determined from single-crystal X-ray diffraction data, collected both at 120 K and at 293 K. The title compound crystallizes in the monoclinic botallackite-type layered structure, space group P2(1), with the lattice parameters a = 5.5776(3) angstrom, b = 6.0733(2) angstrom, c = 18.5134(8) angstrom, beta = 91.802(4)degrees and a = 5.5875(4) angstrom, b = 6.0987(4) angstrom, c = 18.6801(10) angstrom, beta = 91.934(5)degrees for 120 K and for 293 K, respectively. Acetate groups and water molecules are interlayered between corrugated sheets of edge-sharing CuO6 octahedra exhibiting strong distortion resulted from the Jahn-Teller effect. (C) 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码：1051 / 1057
页数：7
相关论文
共 50 条
  • [21] Strontium acetate nitrate trihydrate, [Sr-2(CH3COO)(2)(NO3)(2)(H2O)(3)]
    Lengauer, CL
    Giester, G
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 870 - 872
  • [22] Structure and thermal decomposition of bis (triethanolamine)copper(II) acetate [Cu{N(CH2CH2OH)(3)}(2)](CH3COO)(2)
    Krabbes, I
    Seichter, W
    Breuning, T
    Otschik, P
    Gloe, K
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (09): : 1562 - 1565
  • [23] Synthesis, structure, and properties of [Be(H2O) 4][UO2(CH3COO)3]2
    Klepov V.V.
    Vologzhanina A.V.
    Serezhkina L.B.
    Serezhkin V.N.
    Radiochemistry, 2013, 55 (1) : 36 - 40
  • [24] THE CRYSTAL STRUCTURES OF NICKEL ACETATE, NI(CH3COO)2.4H2O, AND COBALT ACETATE, CO(CH3COO)2.4H2O
    VANNIEKERK, JM
    SCHOENING, FRL
    ACTA CRYSTALLOGRAPHICA, 1953, 6 (07): : 609 - 612
  • [25] Synthesis and crystal structure of (NH4)3[UO2(CH3COO)3]2[UO2(CH3COO)(NCS)2(H2O)]
    L. B. Serezhkina
    E. V. Peresypkina
    A. V. Virovets
    M. O. Karasev
    Crystallography Reports, 2010, 55 : 19 - 23
  • [26] THERMODYNAMIC STABILITY IN THE SERIES OF TRINUCLEAR MU-3-OXOACETATES FE2IIIMNIIO(CH3COO)6(H2O)3 2H2O, FE2IIIFEIIO(CH3COO)6(H2O)3 2H2O, FE2IIICOIIO(CH3COO)6(H2O)3 2H2O, FE2IIINIIIO(CH3COO)6(H2O)3 2H2O, IN THE PROCESS OF THEIR THERMOLYSIS
    YAKUBOV, KM
    NASONOVA, TA
    ABDULLAEV, SK
    THERMOCHIMICA ACTA, 1985, 93 (SEP) : 69 - 71
  • [27] Crystal Structure of Rb-3[UO2(CH3COO)(3)](2)[UO2(CH3COO)(NCS)(2)(H2O)]
    Serezhkina, L. B.
    Vologzhanina, A. V.
    Karasev, M. O.
    Serezhkin, V. N.
    RADIOCHEMISTRY, 2012, 54 (06) : 521 - 524
  • [28] SOLUBILITY IN CO(CH3COO)2-H2O) AND CO(CH3COO)2-H2O SYSTEMS
    ALYMOVA, LN
    LEBEDEVA, ND
    KORF, DM
    ZHURNAL PRIKLADNOI KHIMII, 1970, 43 (08) : 1833 - +
  • [29] Synthesis and crystal structure of copper(II) trifluoroacetates, Cu2(CF3COO)4•2CH3CN and Cu(CF3COO)2(H2O)4
    Karpova, EV
    Boltalin, AI
    Zakharov, MA
    Sorokina, NI
    Korenev, YM
    Troyanov, SI
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (04): : 741 - 744
  • [30] Crystal structure of Rb3[UO2(CH3COO)3]2[UO2(CH3COO)(NCS)2(H2O)]
    L. B. Serezhkina
    A. V. Vologzhanina
    M. O. Karasev
    V. N. Serezhkin
    Radiochemistry, 2012, 54 (6) : 521 - 524
12345