INDO studies on electronic structures of (C8H8)Ln(2,4-C7H11)(THF) (Ln=Nd, Sm, Er)

被引：0

作者：

Wang, ZZ

FENG, JN

Zhang, SB

Liu, JZ

机构：

[1] JILIN UNIV, INST THEORET CHEM, CHANGCHUN 130023, PEOPLES R CHINA

[2] JILIN UNIV, DEPT CHEM, CHANGCHUN 130023, PEOPLES R CHINA

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 1996年 / 12卷 / 02期

关键词：

INDO; electronic structure; rare earth compound;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

INDO SCF calculations on the complexes of (C8H8)Ln(2,4-C7H11) (THF) (Ln = Nd, Sm, Er) indicate that although the f-electrons are essentially Localized on the metal, 5d orbitals,of the metal interact significantly with the ligand orbitals which plays a major role in the bonding. Furthermore, we have discussed the molecular geometries.

引用

页码：151 / 158

页数：8

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