Preparation of 2-phospholene derivatives from zirconacyclopentenes

被引：9
|
作者：
Zhou, Yiging [1 ]
Yan, Xiaoyu [1 ]
Xi, Chanjuan [1 ,2 ]
机构：
[1] Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China
[2] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 47期
基金：
中国国家自然科学基金;
关键词：
Zirconacyclopentenes; Dichlorophosphine; Phospholene; Heterocycles; MOLECULAR-COMPLEX FORMATION; METALLACYCLE TRANSFER; TADDOL DERIVATIVES; PHOSPHOLENE OXIDES; CONVENIENT METHOD; P-HETEROCYCLES; LIGANDS; 1-OXIDES; HYDROFORMYLATION; RESOLUTION;
D O I：
10.1016/j.tetlet.2010.09.061
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Zirconacyclopentenes, which are easily prepared from alkynes, alkenes, and zirconocene compounds, reacted with dichlorophenylphosphine to give 2-phospholene in high yields. The reaction was performed conveniently in one-pot from an alkyne, alkene, dichlorophosphine, and zirconocene compounds. (C) 2010 Elsevier Ltd. All rights reserved.
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页码：6136 / 6138
页数：3
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