Hypervalent phosphorus compounds as ligands

被引：0
|
作者：
Morrow, JR [1 ]
Savino, P [1 ]
Huang, LY [1 ]
Perri, A [1 ]
机构：
[1] SUNY Buffalo, Nat Sci & Math Complex, Dept Chem, Buffalo, NY 14260 USA
来源：
HETEROATOM CHEMISTRY | 1998年 / 9卷 / 07期
关键词：
D O I：
10.1002/(SICI)1098-1071(1998)9:7<699::AID-HC16>3.0.CO;2-P
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four new metal ion complexes with phosphatrane ligands have been isolated and characterized including AuBr3(SP(OCH2CH2)(3)N), AuI3(SP(OCH2CH2)(3)N), AuBr3(OP(OCH2CH2)(3)N) and [MeHg(SP(OCH2CH2)(3)N)](NO3). The phosphatranes are examples of hypervalent phosphorus ligands which ave bound through oxygen or sulfur to the metal ion. These complexes are unique models for proposed intermediates in metal ion promoted phosphate ester substitution reactions. (C) 1998 John Wiley & Sons, Inc.
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页码：699 / 702
页数：4
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