Poly(cyclosiloxane-carborane)s for harsh environments

被引：10

作者：

Zhao, Lihua ^{[1
,2
,3
]}

Li, Tianhao ^{[1
,3
]}

Wang, Bijie ^{[1
,3
]}

Chen, Ke ^{[1
,3
]}

Hu, Xiao ^{[1
,4
]}

Liu, Ming ^{[1
,3
,5
]}

He, Liu ^{[1
,3
]}

Huang, Qing ^{[1
,3
]}

Song, Yujie ^{[1
,3
]}

机构：

[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Engn Lab Adv Energy Mat, Ningbo 315201, Peoples R China

[2] Univ Sci & Technol China, Nanosci & Technol Inst, 166 Renai Rd, Suzhou 215000, Peoples R China

[3] Qianwan Inst CNiTECH, Zhongchuangyi Rd,Hangzhou Bay, Ningbo 315336, Zhejiang, Peoples R China

[4] Nanyang Technol Univ, Sch Mat Sci & Engn, Block N4-1,Nanyang Ave, Singapore 639798, Singapore

[5] Harbin Inst Technol, 92 West Dazhi St, Harbin 150001, Heilongjiang, Peoples R China

来源：

POLYMER CHEMISTRY | 2022年 / 13卷 / 10期

基金：

美国国家科学基金会;

关键词：

ORGANOBORANES; CARBORANES; POLYMERS; SERIES;

D O I：

10.1039/d1py01323h

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(siloxane-carborane)s are a class of polymeric materials which can be used for harsh environments. Poly(cyclosiloxane-carborane)s were prepared through the hydrosilylation of cyclosiloxanes and vinyl modified carboranes. The structure of the as-prepared carborane cyclosiloxane hybrid polymers (CcHPs) could be controlled through changing the ratio of monomers, and the CcHPs showed good thermal stability as well as anti-oxidation properties. The carbon fiber coated with CcHPs could resist high temperature in air, and only 10 wt% loss was observed at 1000 degrees C. The coated carbon foam could retain its shape and size after burning for 2 min, demonstrating the potential applications of CcHPs as protective coatings for harsh environments.

引用

页码：1328 / 1334

页数：8

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