Anodic properties of diarylethene derivatives having organometallic piano-stool tags

被引：12

作者：

Wu, Kan ^{[2
]}

Top, Siden ^{[1
]}

Hillard, Elizabeth A. ^{[1
]}

Jaouen, Gerard ^{[1
]}

Geiger, William E. ^{[2
]}

机构：

[1] Chim ParisTech, LCF, CNRS UMR 7223, F-75005 Paris, France

[2] Univ Vermont, Dept Chem, Burlington, VT 05405 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 36期

基金：

美国国家科学基金会;

关键词：

ESTROGEN-RECEPTOR MODULATORS; QUINONE METHIDES; COMPLEX; ANTIESTROGENS; OXIDATION; ELECTRON; CARBON; SERIES;

D O I：

10.1039/c1cc13787e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The half-sandwich tamoxifen derivative, Mn(CO)(3)(eta(5)-C5H4(Et)C=C(C6H5)(2)), gives a radical cation which is charge-delocalized between the "cymantrenyl" and diphenylethene moieties and undergoes facile metal-carbonyl substitution reactions. Mn and Re complexes with finely tuned redox potentials can be obtained for cancer cell inhibition studies.

引用

页码：10109 / 10111

页数：3