Anodic properties of diarylethene derivatives having organometallic piano-stool tags

被引：12
|
作者：
Wu, Kan [2 ]
Top, Siden [1 ]
Hillard, Elizabeth A. [1 ]
Jaouen, Gerard [1 ]
Geiger, William E. [2 ]
机构：
[1] Chim ParisTech, LCF, CNRS UMR 7223, F-75005 Paris, France
[2] Univ Vermont, Dept Chem, Burlington, VT 05405 USA
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 36期
基金：
美国国家科学基金会;
关键词：
ESTROGEN-RECEPTOR MODULATORS; QUINONE METHIDES; COMPLEX; ANTIESTROGENS; OXIDATION; ELECTRON; CARBON; SERIES;
D O I：
10.1039/c1cc13787e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The half-sandwich tamoxifen derivative, Mn(CO)(3)(eta(5)-C5H4(Et)C=C(C6H5)(2)), gives a radical cation which is charge-delocalized between the "cymantrenyl" and diphenylethene moieties and undergoes facile metal-carbonyl substitution reactions. Mn and Re complexes with finely tuned redox potentials can be obtained for cancer cell inhibition studies.
引用
收藏
页码：10109 / 10111
页数：3
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