One-pot synthesis of Ni nanoparticle/ordered mesoporous carbon composite electrode materials for electrocatalytic reduction of aromatic ketones

被引：14

作者：

Zhang, Zhi-Xia ^{[1
]}

Liu, Yupu ^{[2
]}

Meng, Wang-Jun ^{[1
]}

Wang, Jinxiu ^{[2
]}

Li, Wei ^{[2
]}

Wang, Huan ^{[1
]}

Zhao, Dongyuan ^{[2
]}

Lu, Jia-Xing ^{[1
]}

机构：

[1] East China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

[2] Fudan Univ, iChEM Collaborat Innovat Ctr Chem Energy Mat, Shanghai Key Lab Mol Catalysis & Innovat Mat, Dept Chem,Lab Adv Mat, Shanghai 200433, Peoples R China

来源：

NANOSCALE | 2017年 / 9卷 / 45期

基金：

中国国家自然科学基金;

关键词：

ACTIVE POWDER ELECTRODES; ELECTROCHEMICAL PROPERTIES; POLYMER ELECTROLYTE; MOLECULAR-SIEVES; ACETOPHENONE; HYDROGENATION; COPOLYMER; SILICA; ELECTROCARBOXYLATION; 1-PHENYLETHANOL;

D O I：

10.1039/c7nr06602c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple one-pot synthesis of Ni nanoparticle/ordered mesoporous carbon composite electrode materials is demonstrated for electrosynthesis for the first time. The obtained nanocomposites have uniform mesopore sizes (3.0-3.7 nm), large specific surface areas (506-633 m(2) g(-1)), high pore volumes (0.28-0.38 cm(3) g(-1)), well-graphitized carbon frameworks, and uniformly dispersed Ni nanoparticles (7-15 nm) embedded in the carbon pore walls. The prepared materials show very high performance in the selective (similar to 84%) electrocatalytic reduction of aromatic ketones into alcohols (similar to 79%).

引用

页码：17807 / 17813

页数：7

共 50 条

[31] One-pot synthesis of carbon nanotube-polyaniline-gold nanoparticle and carbon nanotube-gold nanoparticle composites by using aromatic amine chemistry
Guo, Limin
Peng, Zhangquan
LANGMUIR, 2008, 24 (16) : 8971 - 8975
[32] One-pot addition/reduction procedure for the synthesis of γ-amino alcohols from β-enamino ketones
Cimarelli, C
Giuli, S
Palmieri, G
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 2006 (04) : 1017 - 1022
[33] One-pot aerosol synthesis of ordered hierarchical mesoporous core-shell silica nanoparticles
Areva, S
Boissière, C
Grosso, D
Asakawa, T
Sanchez, C
Lindén, M
CHEMICAL COMMUNICATIONS, 2004, (14) : 1630 - 1631
[34] One-pot hydrothermal synthesis of tungsten diselenide/reduced graphene oxide composite as advanced electrode materials for supercapacitors
Gopi, Chandu V. V. Muralee
Reddy, Araveeti Eswar
Bak, Jin-Soo
Cho, In-Ho
Kim, Hee-Je
MATERIALS LETTERS, 2018, 223 : 57 - 60
[35] A one-pot synthesis of 3-arylglutaric anhydrides by reaction of ketene with aromatic aldehydes and ketones
Matsunaga, Hirokazu
Ikeda, Kiyoshi
Iwamoto, Ken-ichi
Suzuki, Yumiko
Sato, Masayuki
TETRAHEDRON LETTERS, 2009, 50 (20) : 2334 - 2336
[36] One-Pot Synthesis of N-Substituted Enaminones from Ketones, Aromatic Nitriles and Halides
Duan, Xiyan
Yang, Shijie
Yao, Changyang
Jia, Fenglin
Wang, Lin
Li, Weinan
Meng, Zhen
Zhou, Yingying
Li, Xiaoqing
CHEMISTRYSELECT, 2019, 4 (44): : 12992 - 12995
[37] One-Pot Synthesis and CO2 Adsorption Properties of Ordered Mesoporous SBA-15 Materials Functionalized with APTMS
Hao, Shiyou
Chang, Hong
Xiao, Qiang
Zhong, Yijun
Zhu, Weidong
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (26): : 12873 - 12882
[38] One-pot synthesis and electrocatalytic characterization of Pt nanoparticle/carbon powder hybrids induced by self-regulated reduction of sodium n-dodecyl sulfate
Lee, Chien-Liang
Wu, Shi-Chi
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2009, 345 (1-3) : 166 - 172
[39] A one-pot hydrothermal synthesis of sulfur and nitrogen doped carbon aerogels with enhanced electrocatalytic activity in the oxygen reduction reaction
Wohlgemuth, Stephanie-Angelika
White, Robin Jeremy
Willinger, Marc-Georg
Titirici, Maria-Magdalena
Antonietti, Markus
GREEN CHEMISTRY, 2012, 14 (05) : 1515 - 1523
[40] A ONE-POT SYNTHESIS OF KETONES AND ALDEHYDES FROM CARBON-DIOXIDE AND ORGANOLITHIUM COMPOUNDS
ZADEL, G
BREITMAIER, E
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (08): : 1035 - 1036

← 1 2 3 4 5 →