Detection of Chlorine in a Non-aqueous Solution via Anodic Oxidation and a Photochemical Reaction

被引：1
|
作者：
Nakagawa, Shogo [1 ,2 ]
Nishimura, Hajime [1 ,3 ]
Kodera, Fumihiro [1 ]
机构：
[1] Asahikawa Coll, Natl Inst Technol, Dept Chem Mat, 2-2-1-6 Shunkodai, Asahikawa, Hokkaido 0718142, Japan
[2] Hokkaido Univ, Grad Sch Environm Sci, Kita Ku, N10W5, Sapporo, Hokkaido 0600810, Japan
[3] Hokkaido Univ, Grad Sch Chem Sci & Engn, Kita Ku, N13W8, Sapporo, Hokkaido 0600810, Japan
来源：
ANALYTICAL SCIENCES | 2018年 / 34卷 / 01期
关键词：
Chlorine; anodic oxidation; photochemical reaction; non-aqueous solution; solvation; H-2/CL-2; FUEL-CELL; PLATINUM-ELECTRODES; REDUCTION REACTION; ACETONITRILE; GAS; PERFORMANCE; KINETICS; HYDROGEN; SENSOR; VOLTAMMETRY;
D O I：
10.2116/analsci.34.1
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
In this study, we developed a new chlorine gas detection method using anodic oxidation and a photochemical reaction. Chlorine gas was temporarily solvated with an aprotic polar solvent having an extensive potential range in the positive direction, and the solvated chlorine molecule was detected by an anodic oxidation reaction. In addition, when combined with ultraviolet light irradiation, we could detect high sensitivity using the photochemical reaction.
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页码：1 / 4
页数：4
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