Heterogeneous catalysts for the controlled ring-opening polymerisation of rac-lactide and homogeneous silsesquioxane model complexes

被引:18
|
作者
Jones, Matthew D.
Davidson, Matthew G.
Keir, Callum G.
Wooles, Ashley J.
Mahon, Mary F. [1 ]
Apperley, David C. [2 ]
机构
[1] Univ Bath, Dept Chem, Bath Chem Crystallog Unit, Bath BA2 7AY, Avon, England
[2] Univ Durham, Dept Chem, Solid State NMR Serv, Durham DH1 3LE, England
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1039/b805274c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In this communication we report, for the first time, the ring-opening polymerisation in the melt of rac-lactide with heterogeneous catalysts. Homogeneous model systems based on silsesquioxanes have been prepared for comparison.
引用
收藏
页码:3655 / 3657
页数:3
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