Zinc(II) Silsesquioxane Complexes and Their Application for the Ring-Opening Polymerization of rac-Lactide

被引：50
|
作者：
Di Iulio, Carlo [1 ]
Jones, Matthew D. [1 ]
Mahon, Mary F. [1 ]
Apperley, David C. [2 ]
机构：
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] Univ Durham, Dept Chem, Solid State NMR Serv, Durham DH1 3LE, England
来源：
INORGANIC CHEMISTRY | 2010年 / 49卷 / 22期
基金：
英国工程与自然科学研究理事会;
关键词：
SURFACE SILANOL SITES; SILICA; CATALYSTS; MODELS; ALUMINUM; DECOMPOSITION; OXYGENATION; RADICALS; LIGANDS; ALKYLS;
D O I：
10.1021/ic101809r
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this Communication, we report the unprecedented solid-state structures for a series of zinc(II) silsesquioxane complexes. Initial catalytic data for the ring-opening polymerization of rac-lactide are also presented together with analogous heterogeneous species.
引用
收藏
页码：10232 / 10234
页数：3
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