Electronic States of Acetic Acid in a Binary Mixture of Acetic Acid and 1-Methylimidazole Depend on the Environment

被引：2

作者：

Yoshimura, Noriko ^{[1
,2
]}

Takahashi, Osamu ^{[2
,3
]}

Oura, Masaki ^{[2
]}

Horikawa, Yuka ^{[1
,2
]}

机构：

[1] Yamaguchi Univ, Grad Sch Sci & Technol Innovat, Yamaguchi 7538512, Japan

[2] RIKEN SPring 8 Ctr, Soft Xray Spect Instrumentat Team, Mikazuki, Hyogo 6795148, Japan

[3] Hiroshima Univ, Dept Chem, Grad Sch Sci, Higashihiroshima 7398526, Japan

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2019年 / 123卷 / 06期

关键词：

RAY-EMISSION SPECTROSCOPY; CARBOXYLIC-ACIDS; LIQUID; SPECTRA; PERFORMANCE; WATER;

D O I：

10.1021/acs.jpcb.8b11437

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The unique characteristics of an acetic acid/1-methylimidazole (1-MI) mixture, showing higher electrical conductivity than either neat acetic acid or neat 1-MI, yet consisting of electrically neutral molecules, are reported. We have applied soft X-ray spectroscopy to reveal the electronic states of acetic acid in the acetic acid/1-MI mixture at various mole fractions of acetic acid (Chi(HOAc)). The results show that the amount of acetic acid monomer increases in the region of especially high electrical conductivity and the amount of complex of acetic acid and 1-MI formed by sharing molecular orbitals increases in the low electrical conductivity region.

引用

页码：1332 / 1339

页数：8

共 50 条

[41] REDUCTION OF TRANSITION METALS WITH ZINC AMALGAM IN GLACIAL ACETIC ACID-ACETIC ANHYDRIDE MIXTURE
PAUL, RC
SINGH, J
PARKASH, R
INDIAN JOURNAL OF CHEMISTRY, 1971, 9 (10): : 1136 - &
[42] Sensory irritation of acetic acid, hydrogen peroxide, peroxyacetic acid and their mixture in mice
Gagnaire, F
Marignac, B
Hecht, G
Héry, M
ANNALS OF OCCUPATIONAL HYGIENE, 2002, 46 (01): : 97 - 102
[43] DETERMINATION OF 1-METHYLIMIDAZOLE-4-ACETIC ACID IN BRAIN-TISSUE FROM RAT AND MOUSE
SWAHN, CG
JOURNAL OF NEUROCHEMISTRY, 1984, 43 (03) : 830 - 834
[44] Solubility, Thermodynamic Properties, and Derived Excess Properties of Benzoic Acid in (Acetic Acid plus Water) and (Acetic Acid plus Toluene) Binary Mixtures
Kumari, Alka
Sandeepa, Kadakanchi
Kumar, Thella Prathap
Satyavathi, Bankupalli
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2016, 61 (01): : 67 - 77
[45] Experimental Investigation of Thermodynamic Properties of Binary Mixture of Acetic acid plus n-Butanol and Acetic acid plus Water at Temperature from 293.15 K to 343.15 K
Paul, M. Danish John
Shruthi, N.
Anantharaj, R.
9TH NATIONAL CONFERENCE ON THERMOPHYSICAL PROPERTIES (NCTP-2017), 2018, 1951
[46] INVESTIGATION OF STRUCTURE OF ACETIC-ACID AND MIXTURE ACETIC ACID CCL4 BY NUCLEAR MAGNETIC-RELAXATION METHOD
BERG, V
HERTZ, HG
TUTSCH, R
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1976, 80 (12): : 1278 - 1284
[47] ISOLATION OF 1-METHYLIMIDAZOLE-4-ACETIC ACID, A METABOLIC PRODUCT OF HISTAMINE, FROM HUMAN URINE
HAM, EA
SCHAYER, RW
BIOCHIMICA ET BIOPHYSICA ACTA, 1963, 71 (01) : 208 - &
[48] Detection of Acetic Acid in wine by means of an electronic nose
Lozano, Jesus
Alvarez, Fernando
Pedro Santos, Jose
Horrillo, Carmen
OLFACTION AND ELECTRONIC NOSE: PROCEEDINGS OF THE 14TH INTERNATIONAL SYMPOSIUM ON OLFACTION AND ELECTRONIC NOSE, 2011, 1362 : 176 - +
[49] The viscosities of binary mixtures of the associated liquids, water, formic acid and acetic acid
Davis, PB
Jones, HC
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1915, 37 : 1194 - 1198
[50] COULOMETRIC GENERATION OF ACETYL IONS BY OXIDATION OF MERCURY IN ACETIC-ANHYDRIDE AND IN ACETIC-ACID ACETIC-ANHYDRIDE MIXTURE
VAJGAND, V
MIHAJLOVIC, R
MIHAJLOVIC, L
JOKSIMOVIC, V
ANALYTICA CHIMICA ACTA, 1988, 212 (1-2) : 73 - 79

← 1 2 3 4 5 →