Experimental and Quantum Chemical Approaches to Develop Highly Selective Nanocatalysts for CO2-free Power Circulation

被引：16
|
作者：
Yamauchi, Miho [1 ]
Ozawa, Nobuki [2 ]
Kubo, Momoji [2 ]
机构：
[1] Kyushu Univ, Int Inst Carbon Neutral Energy Res WPI I2CNER, Nishi Ku, Motooka 744, Fukuoka 8190395, Japan
[2] Tohoku Univ, Inst Mat Res, Aoba Ku, 2-1-1 Katahira, Sendai, Miyagi 9808577, Japan
来源：
CHEMICAL RECORD | 2016年 / 16卷 / 05期
关键词：
carbon-neutral; density functional calculations; electrocatalysts; Fe-group nanoalloys; titanium; ETHYLENE-GLYCOL; HYDROGEN STORAGE; ELECTROCATALYTIC OXIDATION; STRUCTURAL TRANSFORMATION; ALLOY NANOPARTICLES; BIMETALLIC SURFACES; CATALYST; ELECTROOXIDATION; REDUCTION; METHANOL;
D O I：
10.1002/tcr.201600047
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Renewable electricity must be utilized to usefully suppress the atmospheric CO2 concentration and slow the progression of global warming. We have thus proposed a new concept involving CO2-free electric power circulation systems via highly selective electrochemical reactions of alcohol/carboxylic acid redox couples. Design concepts for nanocatalysts able to catalyze highly selective electrochemical reactions are provided from both experimental and quantum mechanical perspectives.
引用
收藏
页码：2249 / 2259
页数：11
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