Tandem aldol-allylation reactions: Double C-C bond formation using silicon-tethered dinucleophiles

被引：13
|
作者：
Frost, LM
Smith, JD
Berrisford, DJ
机构：
[1] Univ Manchester, Inst Sci & Technol, Dept Chem, Manchester M60 1QD, Lancs, England
[2] Pfizer Ltd, Cent Res, Proc Res & Dev, Sandwich CT13 9NJ, Kent, England
来源：
TETRAHEDRON LETTERS | 1999年 / 40卷 / 11期
关键词：
acetals; aldol reactions; allylation; silicon and compounds;
D O I：
10.1016/S0040-4039(98)02126-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new tandem C-C bond forming process has been developed which utilises silicon-tethered dinucleophiles and acetals under Lewis acid conditions. The reaction incorporates a functionalised five carbon unit into both aromatic and aliphatic acetals, affording acyclic beta-alkoxyhomoallylic alcohols in good yields. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2183 / 2186
页数：4
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