Synthesis of novel hydroperoxy-substituted 1,2,4,5-tetroxepanes and 1,2,4,5-tetroxocanes

被引：5
|
作者：
Nonami, Y
Ushigoe, Y
Masuyama, A
Nojima, M
McCullough, KJ
机构：
[1] Osaka Univ, Fac Engn, Dept Chem Mat, Suita, Osaka 565, Japan
[2] Heriot Watt Univ, Dept Chem, Edinburgh EH14 4AS, Midlothian, Scotland
来源：
TETRAHEDRON LETTERS | 1998年 / 39卷 / 36期
关键词：
D O I：
10.1016/S0040-4039(98)01375-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Ozonolysis of vinyl ether 1 in the presence of unsaturated hydroperoxides 3 gave the corresponding unsaturated hydroperoxy peracetals 4, which in turn reacted with ozone in acetic acid to give the novel hydroperoxy-substituted cyclic peroxides containing two peroxide groups in the ring. The structure of 1-methyl-4-phenyl-2,3,5,6-tetroxocanyl hydroperoxide 12 was unambiguously determined by the X-ray analysis, (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：6597 / 6600
页数：4
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