Heterocyclic synthesis using nitrilimines: Part 3(1). Synthesis of substituted 1,2,4,5-tetrazines and 1,2,4,5-tetraaza-2-pentenes.

被引：0
|
作者：
Dalloul, HM [1 ]
Boyle, PH [1 ]
机构：
[1] Trinity Coll Dublin, Dept Chem, Dublin 2, Ireland
来源：
HETEROCYCLIC COMMUNICATIONS | 2003年 / 9卷 / 05期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of nitrilimines 2a,b with hydrazones of aliphatic ketones 3 (RHNN==(CRR2)-R-1) led to the formation of the cyclocondensation products 1,2,4,5-tetrazines 4a-g when R = CH3, and to acyclic electrophilic addition products 5a-g when R = H, rather than the cyclocondensation tetrazines products 8.
引用
收藏
页码：507 / 514
页数：8
相关论文
共 50 条
  • [1] Heterocyclic synthesis using nitrilimines-part 1 - Synthesis of substituted dihydro- and tetrahydro-1,2,4,5-tetrazines
    Dalloul, HM
    Abu-Dia, YM
    El-Sawi, AE
    [J]. ASIAN JOURNAL OF CHEMISTRY, 2003, 15 (03) : 1320 - 1326
  • [2] Synthesis of 1,2,4,5-tetrazines
    Singh, R
    Choubey, AK
    Shukla, AK
    Singh, PK
    [J]. INDIAN JOURNAL OF HETEROCYCLIC CHEMISTRY, 1998, 7 (03) : 173 - 176
  • [3] Synthesis of monosubstituted 1,2,4,5-tetrazines – 3-amino-1,2,4,5-tetrazines
    Gennady F. Rudakov
    Yurii A. Moiseenko
    Natal’ya А. Spesivtseva
    [J]. Chemistry of Heterocyclic Compounds, 2017, 53 : 802 - 810
  • [4] 2 HETEROCYCLIC 1,2,4,5-TETRAZINES
    YEH, MY
    HUANG, CY
    UENG, CH
    WANG, Y
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 1781 - 1784
  • [5] Synthesis of monosubstituted 1,2,4,5-tetrazines-3-amino-1,2,4,5-tetrazines
    Rudakov, Gennady F.
    Moiseenko, Yurii A.
    Spesivtseva, Natal'ya A.
    [J]. CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2017, 53 (6-7) : 802 - 810
  • [6] Heterocyclic synthesis using nitrilimines: Part 10. Synthesis of some new 1,3,4,6-tetrasubstituted 1,2,4,5-tetrazines
    Dalloul, Hany M.
    Abu-Shawish, Hazem M.
    [J]. ORGANIC COMMUNICATIONS, 2008, 1 (01) : 1 - 8
  • [7] 1,2,4,5-Tetrazines and Azolo[1,2,4,5]tetrazines: Synthesis and Reactions with Nucleophiles
    S. G. Tolshchina
    G. L. Rusinov
    V. N. Charushin
    [J]. Chemistry of Heterocyclic Compounds, 2013, 49 : 66 - 91
  • [8] 1,2,4,5-Tetrazines and Azolo[1,2,4,5]tetrazines: Synthesis and Reactions with Nucleophiles
    Tolshchina, S. G.
    Rusinov, G. L.
    Charushin, V. N.
    [J]. CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2013, 49 (01) : 66 - 91
  • [9] SYNTHESIS OF IMIDAZO[1,2,4,5]TETRAZINES AND DIIMIDAZO[1,2,4,5]TETRAZINES - FOR TAUTOMERISM OF DIHYDRO-1,2,4,5-TETRAZINES
    WAMHOFF, H
    STROBL, HW
    JANSEN, M
    RALLE, M
    [J]. SYNTHESIS-STUTTGART, 1992, (09): : 879 - 883
  • [10] Synthesis of 5-trifluoromethylpyrazol-1-yl-substituted 1,2,4,5-tetrazines
    S. G. Tolshchina
    N. K. Ignatenko
    P. A. Slepukhin
    R. I. Ishmetova
    G. L. Rusinov
    [J]. Chemistry of Heterocyclic Compounds, 2010, 46 : 691 - 698
12345