Solvent effect on the free-radical copolymerization of 2-hydroxyethyl methacrylate with t-butyl acrylate

被引：26
|
作者：
Fernández-Monreal, C
Martínez, G
Sánchez-Chaves, M
Madruga, EL
机构：
[1] Univ Complutense Madrid, Dept Quim Organ 1, E-28040 Madrid, Spain
[2] CSIC, Inst Ciencia & Tecnol Polimeros, E-28006 Madrid, Spain
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2001年 / 39卷 / 12期
关键词：
2-hydroxyethyl methacrylate; t-butyl acrylate; radical copolymerization; reactivity ratios; solvent effects; bootstrap effect; hydrogen bonding;
D O I：
10.1002/pola.1180
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The free-radical copolymerization of 2-hydroxyethyl methacrylate with t-butyl acrylate was carried out at 50 degreesC in bulk and in 3 mol.L-1 1,4-dioxane and N,N ' -dimethylformamide solutions. Differences between the apparent reactivity ratios determined in this work indicated a noticeable solvent effect. This is explained with a qualitative bootstrap effect. (C) 2001 John Wiley & Sons, Inc.
引用
收藏
页码：2043 / 2048
页数：6
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