Synthesis and crystal structure of tert-butyl 2-((phenylthio)-carbonyl)pyrrolidine-1-carboxylate

被引：2
|
作者：
Naveen, S.
Dinesh, B.
Abiraj, K.
Gowda, D. Channe
Sridhar, M. A. [1 ]
Prasad, J. Shashidhara
机构：
[1] Univ Mysore, Dept Studies Phys, Mysore 570006, Karnataka, India
[2] Univ Mysore, Dept Studies Chem, Mysore 570006, Karnataka, India
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2007年 / 37卷 / 11期
关键词：
thiol ester; anhydride method; envelope conformation;
D O I：
10.1007/s10870-007-9239-0
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Tert-butyl 2-((phenylthio)carbonyl)pyrrolidine-1-carboxylate, was synthesized by using iso-butoxycarbonyl chloride (i-BuOCOCl) via mixed anhydride method. The obtained product was characterized spectroscopically and finally confirmed by X-ray diffraction studies. The title compound C-16 H-21 N O-3 S crystallizes in the triclinic space group P1 with the cell parameters a = 6.0250(7) angstrom, b = 8.2820(13), c = 8.7700(14) angstrom, c = 102.352(4)angstrom, alpha= 102.993(11)degrees, gamma= 90.279(8)degrees, V = 415.89(10) A(3) and Z = 1. The proline ring in the structure is in a envelope conformation. The structure exhibits intermolecular hydrogen bonds of the type C-H...O.
引用
收藏
页码：721 / 725
页数：5
相关论文
共 50 条
  • [31] tert-Butyl 4-[2-(methoxycarbonyl)ethyl-3.5-dimethyl-1H-pyrrole-2-carboxylate
    Silva, MR
    Beja, AAM
    Paixao, JA
    Lopes, SH
    Cabral, AMTDPV
    Gonsalves, AMDR
    Sobral, AJFN
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O575 - O577
  • [32] EFFICIENT SYNTHESIS OF METHYL 2-(TERT-BUTYL)ACRYLATE AND ANALOGOUS ESTERS
    XU, LH
    KUNDIG, EP
    HELVETICA CHIMICA ACTA, 1994, 77 (06) : 1480 - 1484
  • [33] Chemoselective N-deprotection of tert-butyl 2-(trifluoroacetylamino) esters under PTC conditions: synthesis of tert-butyl 2-aminocarboxylates
    J Chem Soc Perkin Trans 1, 3 (247):
  • [34] Chemoselective N-deprotection of tert-butyl 2-(trifluoroacetylamino) esters under PTC conditions: Synthesis of tert-butyl 2-aminocarboxylates
    Albanese, D
    Corcella, F
    Landini, D
    Maia, A
    Penso, M
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (03): : 247 - 249
  • [35] The crystal structure of tert-butyl (E)-3-(2-(benzylideneamino)phenyl)-1H-indole-1-carboxylate, C26H24N2O2
    Da, Weihao
    Kong, Haonan
    Wang, Ruiyao
    Lin, Yi
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2023, 238 (05): : 837 - 839
  • [36] Synthesis and coordination of a tert-butyl functionalized facially coordinating 2-histidine-1-carboxylate model ligand
    Gunasekera, Parami S.
    MacMillan, Samantha N.
    Lacy, David C.
    JOURNAL OF COORDINATION CHEMISTRY, 2021, 74 (1-3) : 315 - 320
  • [37] Regioselective-γ-Alkylation of tert-Butyl 2,4-Dioxopiperidine-1-carboxylate
    Orsini, Paolo
    Maccario, Alessandro
    Colombo, Nicoletta
    SYNTHESIS-STUTTGART, 2007, 20 (20): : 3185 - 3190
  • [38] tert-Butyl 4-(2-diazoacetyl)piperazine-1-carboxylate
    Kaupang, Asmund
    Gorbitz, Carl Henrik
    Hansen, Tore
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O2199 - U467
  • [39] Copper-catalyzed direct trifluoromethylthiolation of indoles by tert-butyl 2-((trifluoromethyl)sulfonyl)hydrazine-1-carboxylate
    Lu, Kui
    Li, Quan
    Xi, Xiaolan
    Huang, Yuna
    Gong, Zhi
    Yu, Peng
    Zhao, Xia
    ORGANIC CHEMISTRY FRONTIERS, 2018, 5 (21): : 3088 - 3092
  • [40] Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxy-benzylidene]-N-cyclohexylhydrazine-1-carbothioamide
    Arafath, Md Azharul
    Kwong, Huey Chong
    Adam, Farook
    Razali, Mohd R.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 1460 - +
12345