Synthesis and crystal structure of tert-butyl 2-((phenylthio)-carbonyl)pyrrolidine-1-carboxylate

被引：2
|
作者：
Naveen, S.
Dinesh, B.
Abiraj, K.
Gowda, D. Channe
Sridhar, M. A. [1 ]
Prasad, J. Shashidhara
机构：
[1] Univ Mysore, Dept Studies Phys, Mysore 570006, Karnataka, India
[2] Univ Mysore, Dept Studies Chem, Mysore 570006, Karnataka, India
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2007年 / 37卷 / 11期
关键词：
thiol ester; anhydride method; envelope conformation;
D O I：
10.1007/s10870-007-9239-0
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Tert-butyl 2-((phenylthio)carbonyl)pyrrolidine-1-carboxylate, was synthesized by using iso-butoxycarbonyl chloride (i-BuOCOCl) via mixed anhydride method. The obtained product was characterized spectroscopically and finally confirmed by X-ray diffraction studies. The title compound C-16 H-21 N O-3 S crystallizes in the triclinic space group P1 with the cell parameters a = 6.0250(7) angstrom, b = 8.2820(13), c = 8.7700(14) angstrom, c = 102.352(4)angstrom, alpha= 102.993(11)degrees, gamma= 90.279(8)degrees, V = 415.89(10) A(3) and Z = 1. The proline ring in the structure is in a envelope conformation. The structure exhibits intermolecular hydrogen bonds of the type C-H...O.
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收藏
页码：721 / 725
页数：5
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