Role of montmorillonite in flame retardancy of ethylene-vinyl acetate copolymer

被引：70

作者：

Szép, A ^{[1
]}

Szabó, A ^{[1
]}

Tóth, N ^{[1
]}

Anna, P ^{[1
]}

Marosi, G ^{[1
]}

机构：

[1] Budapest Univ Technol & Econ, Dept Organ Chem Technol, H-1111 Budapest, Hungary

来源：

POLYMER DEGRADATION AND STABILITY | 2006年 / 91卷 / 03期

关键词：

nanocomposite; hydrated filler; interface modification; fire retardancy; thermal degradation; rheology;

D O I：

10.1016/j.polymdegradstab.2005.02.026

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The effects of non-treated (MMT), organophilic (OMM), and olefin/silicone polymer intercalated (IMM) montmorillonites on the thermal stability of ethylene-vinyl acetate copolymer (EVA) and on the flammability of magnesium hydroxide filled EVA were studied. The influence of various treatments oil the delamination of montmorillonites in EVA was detected by rheological Measurements and by Raman microscopy. The latter was a unique method for rapid detection of the dispersion also in highly filled EVA. Enhancement of thermo-oxidative stability of EVA and flame-retarded EVA could be observed by thermal analysis in the presence of variously treated montmorillonites. The flame-retardant efficiency of magnesium hydroxide was improved by simultaneous application of MMT and IMM. The increased performance of magnesium hydroxide was explained by the rheological effect of the IMM, catalytic effect of MMT and chemical interactions of montmorillonites with the metal hydroxide. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：593 / 599

页数：7

共 50 条

[21] Synergistic properties of microencapsulated intumescent flame retardant-organically modified montmorillonite/ethylene-vinyl acetate copolymer composites
Li Z.
Cheng W.
Dong C.
Wang B.
Jin Z.
Fang Q.
Hu Y.
Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica, 2021, 38 (08): : 2546 - 2553
[22] PREPARATION OF POWDERED ETHYLENE-VINYL ACETATE COPOLYMER
TSUCHIHARA, T
KOBUNSHI RONBUNSHU, 1980, 37 (01) : 15 - 21
[23] PEROXIDE CROSSLINKING OF ETHYLENE-VINYL ACETATE COPOLYMER
NARKIS, M
MILTZ, J
JOURNAL OF APPLIED POLYMER SCIENCE, 1977, 21 (03) : 703 - 709
[24] ALKALINE SAPONIFICATION OF ETHYLENE-VINYL ACETATE COPOLYMER
IWASAKI, H
YONEZU, K
KOBUNSHI RONBUNSHU, 1978, 35 (01) : 33 - 39
[25] Ethylene-Vinyl Acetate/LDH Nanocomposites With Enhanced Thermal Stability, Flame Retardancy, and Rheological Property
Gao, Yanshan
Wang, Qiang
Qiu, Lei
Wu, Jingwen
Yan, Xingru
Umar, Ahmad
Guo, Jiang
Zhang, Xi
Wang, Junya
Guo, Zhanhu
POLYMER COMPOSITES, 2016, 37 (12) : 3449 - 3459
[26] Effects of Magnesium Hydroxide on the Flame Retardancy of Ethylene-Vinyl Acetate Copolymers/Nitrile Rubber Blends
Wang, He
Shi, Xinyan
Zhao, Shugao
JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS, 2014, 53 (05): : 769 - 780
[27] Study of nanocarbon black as synergist on improving flame retardancy of ethylene-vinyl acetate/brucite composites
Zhiqi Liu
Yanling Zhang
Na Li
Xin Wen
Luis Arevalo Nogales
Lijuan Li
Fan Guo
Journal of Thermal Analysis and Calorimetry, 2019, 136 : 601 - 608
[28] Study of nanocarbon black as synergist on improving flame retardancy of ethylene-vinyl acetate/brucite composites
Liu, Zhiqi
Zhang, Yanling
Li, Na
Wen, Xin
Arevalo Nogales, Luis
Li, Lijuan
Guo, Fan
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2019, 136 (02) : 601 - 608
[29] Magnesium hydroxide nanoparticles grafted by DOPO and its flame retardancy in ethylene-vinyl acetate copolymers
Liu, Tingting
Wang, Feng
Li, Gen
Liu, Peng
Gao, Chong
Ding, Yanfen
Zhang, Shimin
Kong, Xiangrong
Yang, Mingshu
JOURNAL OF APPLIED POLYMER SCIENCE, 2021, 138 (01)
[30] A New Method for Estimating the Content of Vinyl Acetate in Ethylene-Vinyl Acetate Copolymer
Izutsu, Tomoyuki
Odaka, Daisuke
Komatsu, Marina
Ohki, Yoshimichi
Mizuno, Maya
Nakamura, Yoshiaki
Chiwata, Naofumi
IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION, 2016, 23 (03) : 1260 - 1265

← 1 2 3 4 5 →