Synthesis, characterization and catalytic activity of magnesium and zinc aminophenoxide complexes: Catalysts for ring-opening polymerization of L-lactide

被引：37
|
作者：
Chuang, Hui-Ju [1 ]
Weng, Shi-Feng [1 ]
Chang, Chia-Chih [1 ]
Lin, Chu-Chieh [1 ]
Chen, Hsuan-Ying [2 ]
机构：
[1] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan
[2] Kaohsiung Med Univ, Dept Med & Appl Chem, Kaohsiung 80708, Taiwan
来源：
DALTON TRANSACTIONS | 2011年 / 40卷 / 37期
关键词：
ALKOXIDE-INITIATED POLYMERIZATIONS; CHAIN-END CONTROL; EPSILON-CAPROLACTONE; STEREOSELECTIVE POLYMERIZATION; EFFICIENT CATALYSTS; RACEMIC LACTIDE; COORDINATION POLYMERIZATION; IMMORTAL POLYMERIZATION; ALUMINUM; LITHIUM;
D O I：
10.1039/c1dt11080b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of novel magnesium and zinc aminophenoxide complexes were successfully synthesized and one zinc complex was characterized by X-ray crystallography. They were also investigated as initiators for the ring opening polymerization of L-lactide. The complexes are effective in forming polylactides with good conversions. The nature and steric bulk of the ligands coordinated to the central metal ions enormously influenced the polymer properties. Among all the complexes, the zinc aminophenoxide complexes as initiators produced polymers with good molecular weight control and relatively narrow PDIs.
引用
收藏
页码：9601 / 9607
页数：7
相关论文
共 50 条
  • [41] Poly(L,L-lactide) microspheres by ring-opening polymerization
    Sosnowski, S
    Gadzinowski, M
    Slomkowski, S
    MACROMOLECULES, 1996, 29 (13) : 4556 - 4564
  • [42] Zinc complexes supported by N,O-bidentate amino-alkoxyl ligands: Synthesis, characterization and catalytic property for the ring-opening polymerization of L-lactide
    Han, Yancheng
    Gao, Aihong
    Zhang, Yongfang
    Yao, Wei
    Guan, Haibin
    POLYHEDRON, 2018, 139 : 243 - 248
  • [43] Ring-opening polymerization of L-lactide catalyzed by robust magnesium-sodium/lithium heterobimetallic complexes
    Wang, Lei
    Zhang, Jinfeng
    Yao, Lihui
    Tang, Ning
    Wu, Jincai
    INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (06) : 859 - 862
  • [44] Synthesis and structures of N-arylcyano-β-diketiminate zinc complexes and adducts and their application in ring-opening polymerization of L-lactide
    Trofymchuk, Oleksandra S.
    Daniliuc, Constantin G.
    Kehr, Gerald
    Erker, Gerhard
    Rojas, Rene S.
    RSC ADVANCES, 2015, 5 (27) : 21054 - 21065
  • [45] The ring-opening polymerization of ε-caprolactone and L-lactide using aluminum complexes bearing benzothiazole ligands as catalysts
    Huang, Yen-Tzu
    Wang, Wei-Chu
    Hsu, Chun-Pin
    Lu, Wei-Yi
    Chuang, Wan-Jung
    Chiang, Michael Y.
    Lai, Yi-Chun
    Chen, Hsuan-Ying
    POLYMER CHEMISTRY, 2016, 7 (26) : 4367 - 4377
  • [46] Catalytic improvement of titanium complexes bearing bis(aminophenolate) in ring-opening polymerization of L-lactide and ε-caprolactone
    Ou, Hsiu-Wei
    Chen, Hsing-Yin
    Tseng, His-Ching
    Hsiao, Mon-Wei
    Chang, Yu-Lun
    Jheng, Nai-Yuan
    Lai, Yi-Chun
    Shih, Tzung-Yu
    Lin, Yu-Ting
    Chen, Hsuan-Ying
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 394 : 97 - 104
  • [47] Zinc/magnesium-sodium/lithium heterobimetallic triphenolates: Synthesis, characterization, and application as catalysts in the ring-opening polymerization of L-lactide and CO2/epoxide coupling
    Sun, Yangyang
    Wang, Lei
    Yu, Dawei
    Tang, Ning
    Wu, Jincai
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 393 : 175 - 181
  • [48] Preparation and characterization of bisphenolato magnesium derivatives: an efficient catalyst for the ring-opening polymerization of ε-caprolactone and L-lactide
    Shen, Min-Yi
    Peng, Ya-Liu
    Hung, Wen-Chou
    Lin, Chu-Chieh
    DALTON TRANSACTIONS, 2009, (44) : 9906 - 9913
  • [49] SYNTHESIS AND CHARACTERIZATION OF CELLULOSE-GRAFT-POLY (L-LACTIDE) VIA RING-OPENING POLYMERIZATION
    Xiao, Shu
    Yuan, Tongqi
    Cao, Huibo
    Lin, Dai
    Shen, Yue
    He, Jing
    Wang, Bo
    BIORESOURCES, 2012, 7 (02): : 1748 - 1759
  • [50] Aluminum Salen Complexes Modified with Unsaturated Alcohol: Synthesis, Characterization, and Their Activity towards Ring-Opening Polymerization of ε-Caprolactone and D,L-Lactide
    Zaitsev, Kirill V.
    Trubachev, Andrey D.
    Oprunenko, Yuri F.
    Piskun, Yuliya A.
    Vasilenko, Irina V.
    Churakov, Andrei V.
    Kostjuk, Sergei V.
    MOLECULES, 2023, 28 (03):
12345