Synthesis, structure, and mass spectral study of coordination compounds of manganese(II) diisobutyldithiophosphinate with 2,2-bipyridine and o-phenanthroline

被引：0
|
作者：
Kokina, TE [1 ]
Glinskaya, LA [1 ]
Klevtsova, RF [1 ]
Semyannikov, PP [1 ]
Trubin, SV [1 ]
Larionov, SV [1 ]
机构：
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 48卷 / 06期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The high-spin compounds [(Mn(2,2'-Bipy)(i-Bu2PS2)(2)] (1) and [Mn(Phen)(i-Bu2PS2)(2)] (11) with mu(eff) = 5.90 (I) and 5.92 (II) mu(B) have been synthesized. The structure of complex I has been determined by X-ray diffraction. The crystals are monoclinic: a = 14.723(3) Angstrom, b = 20.940(3) Angstrom, c = 11.385(2) Angstrom, beta = 105.61(1)degrees, V = 3380(1) Angstrom(3), Z = 4, rho(calcd) = 1.237 g/cm(3), space group P2(1)/c. Complex I has a molecular mononuclear structure. The Mn coordination polyhedron is a distorted octahedron, MnN2S4. The 2,2'-Bipy molecules of two neighboring complexes are involved in a pi-pi interaction giving rise to dimeric molecular ensembles. The mass spectra of complexes I and II show molecular ions for the Mn(i-Bu2PS2)(2) chelate and for heterocycles. The [MnS](+) ion is formed amoncy the fragmentation products of the [Mn(i-Bu2PS2)(2)](+) molecular ion. Thermodynamic parameters for vaporization of Mn(i-Bu2PS2)(2) have been determined.
引用
收藏
页码：817 / 825
页数：9
相关论文
共 50 条
  • [41] Synthesis, characterization, spectroscopic study, and catalytic behavior of ruthenium(II) o-phenanthroline complex with dipicolinate
    Jameh-Bozorghi, Saeed
    Esfandiari, Hadi
    Saravani, Hamideh
    Charati, Faramarz Rostami
    Skelton, Brian W.
    Makha, Mohamed
    JOURNAL OF COORDINATION CHEMISTRY, 2012, 65 (06) : 994 - 1003
  • [42] A New 3D Manganese(II) Coordination Polymer with 4,4-Dicarboxy-2,2′-bipyridine and 1,10-Phenanthroline: Synthesis, Structural, and Magnetic Properties
    Cao, Ting-Ting
    Ma, Yue
    Yang, Chun
    Liao, Dai-Zheng
    Yan, Shi-Ping
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (15): : 2704 - 2708
  • [43] A pulse radiolysis study on the reactivity of COOH/CO2- radicals and o-phenanthroline and 2,2'-bipyridine electron adducts to uranyl and neptunyl ions in aqueous solutions
    Gogolev, AV
    Shilov, VP
    Pikaev, AK
    HIGH ENERGY CHEMISTRY, 1996, 30 (05) : 349 - 351
  • [44] A Pulse Radiolysis Study on the Reactivity of COOH/CO-2 Radicals and o-Phenanthroline and 2,2'-Bipyridine Electron Adducts to Uranyl and Neptunyl Ions in Aqueous Solutions
    Gogolev, A. V.
    Shilov, V. P.
    Pikaev, A. K.
    High Energy Chemistry, 30 (05):
  • [45] Synthesis and Structure of Cytotoxic Copper(II) Complexes Based on di(o-tolyl)Phosphinic Acid and 2,2'-Bipyridine/1,10-Phenanthroline
    Savinykh, P. E.
    Golubeva, Y. A.
    Smirnova, K. S.
    Klyushova, L. S.
    Davydova, M. P.
    Artemiev, A. V.
    Lider, E. V.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2024, 65 (07) : 1465 - 1476
  • [46] Synthesis, characterization and structure assessment of mononuclear and binuclear low-spin manganese(II) complexes derived from oxaloyldihydrazones, 1,10-phenanthroline and 2,2′-bipyridine
    Syiemlieh, Ibanphylla
    Kumar, Arvind
    Kurbah, Sunshine D.
    Lal, Ram A.
    JOURNAL OF MOLECULAR STRUCTURE, 2018, 1166 : 252 - 261
  • [47] Synthesis and structure of bis(π-cyclopentadienyl)vanadium(IV) 1,10-phenanthroline and 2,2′-bipyridine compounds and their interactions with artificial membranes
    Ghosh, P
    Kotchevar, AT
    DuMez, DD
    Ghosh, S
    Peiterson, J
    Uckun, FM
    INORGANIC CHEMISTRY, 1999, 38 (16) : 3730 - 3737
  • [48] Synthesis and crystal structure of copper(II) 2,2,6,6-tetramethylheptan-3,5-dionate adduct with o-phenanthroline
    Troyanov, SI
    Gorbenko, OY
    Bosak, AA
    POLYHEDRON, 1997, 16 (10) : 1595 - 1598
  • [49] Six Coordinate Transition Metal (II) Complexes of Mixed Ligands of Eflornithine Hydrochloride Hydrate and 2,2-Bipyridine: Synthesis, Characterization and Antibacterial Study
    Osunniran, Wahab A.
    Obaleye, Joshua A.
    Ayipo, Yusuf O.
    Rajee, Abdullahi O.
    Enemose, Edith A.
    JORDAN JOURNAL OF CHEMISTRY, 2018, 13 (03) : 149 - 157
  • [50] Structure and spectral properties of TCNQ salts with Zn(II) and Ni(II) 2,2′-bipyridine complexes
    Vasylets, Grygorii Y.
    Starodub, Vladimir A.
    Barszcz, Boleslaw
    Graja, Andrzej
    Medviediev, Volodymyr V.
    Shishkin, Oleg V.
    Bukrinev, Alexander S.
    SYNTHETIC METALS, 2014, 191 : 89 - 98
12345