Carbon Dioxide Hydrogenation to Formic Acid by Using a Heterogeneous Gold Catalyst

被引：241
|
作者：
Preti, Debora [1 ]
Resta, Claudio [1 ]
Squarcialupi, Sergio [2 ]
Fachinetti, Giuseppe [1 ]
机构：
[1] Univ Pisa, Dipartimento Chim, I-56126 Pisa, Italy
[2] Chimet SpA, I-52041 Badia Al Pino, Italy
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 52期
关键词：
C1; chemistry; carbon dioxide; formic acid; gold catalysts; hydrogenation; STORAGE MATERIAL; GENERATION; DECOMPOSITION; COMPLEXES; ADDUCTS; CO2;
D O I：
10.1002/anie.201105481
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
AUROlite, consisting of gold supported on titania (picture shows extrudates in a steel net cage), is a robust catalyst for the production of catalyst-free HCOOH/NEt 3 adducts from H 2, CO 2, and neat NEt 3. Pure HCOOH is freed from the adducts by amine exchange. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页码：12551 / 12554
页数：4
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