(2,3-Di-2-pyridylpyrazine-κ2N2,N3)diiodidopalladium(II)

被引：6

作者：

Ha, Kwang ^{[1
]}

机构：

[1] Chonnam Natl Univ, Sch Appl Chem Engn, Res Inst Catalysis, Kwangju 500757, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

基金：

新加坡国家研究基金会;

关键词：

D O I：

10.1107/S1600536811044023

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The Pd-II ion in the title complex, [PdI2(C14H10N4)], is four-coordinated in a slightly distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridylpyrazine (dpp) ligand and two iodide anions. In the crystal, the pyridine rings are considerably inclined to the least-squares plane of the PdI2N2 unit [maximum deviation = 0.090 (2) angstrom], making dihedral angles of 65.0 (2) and 66.6 (2)degrees. The pyrazine ring is perpendicular to the unit plane, with a dihedral angle of 89.9 (2)degrees. The complex molecules are connected by C-H center dot center dot center dot I hydrogen bonds, forming a helical chain along the b axis.

引用

页码：M1626 / +

页数：10

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