Regularities of glycidol synthesis by the liquid-phase epoxidation of allyl alcohol with hydrogen peroxide

被引:1
|
作者
Sulimov, A. V. [1 ]
Danov, S. M. [1 ]
Ovcharova, A. V. [1 ]
Ovcharov, A. A. [1 ]
Flid, V. R. [2 ]
机构
[1] RE Alekseev Nizhny Novgorod State Tech Univ, Nizhnii Novgorod 603950, Russia
[2] MV Lomonosov Moscow State Univ Fine Chem Technol, Moscow 119571, Russia
关键词
glycidol; allyl alcohol; hydrogen peroxide; epoxidation; titanium-containing zeolite TS-1;
D O I
10.1007/s11172-014-0793-2
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The main features of the liquid-phase epoxidation of allyl alcohol by hydrogen peroxide in an organic solvent in the presence of the titanium-containing zeolite in the batch reactor were studied. The influence of the amount of the solvent, ratio of reactants, and temperature on the rate of glycidol synthesis was revealed.
引用
收藏
页码:2647 / 2651
页数:5
相关论文
共 50 条
  • [21] A Kinetic Model for the Epoxidation of Allyl Alcohol with Hydrogen Peroxide on Titanium Silicate TS-1
    A. V. Sulimov
    S. M. Danov
    A. V. Ovcharova
    V. R. Flid
    L. G. Bruk
    Kinetics and Catalysis, 2017, 58 : 673 - 678
  • [22] A Kinetic Model for the Epoxidation of Allyl Alcohol with Hydrogen Peroxide on Titanium Silicate TS-1
    Sulimov, A. V.
    Danov, S. M.
    Ovcharova, A. V.
    Flid, V. R.
    Bruk, L. G.
    KINETICS AND CATALYSIS, 2017, 58 (06) : 673 - 678
  • [23] Liquid-phase synthesis of cyclic diene diepoxides using metal halides and hydrogen peroxide
    Alimardanov, Kh. M.
    Sadygov, O. A.
    Garibov, N. I.
    Abdullaeva, M. Ya.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2012, 48 (10) : 1302 - 1308
  • [24] Liquid-phase synthesis of cyclic diene diepoxides using metal halides and hydrogen peroxide
    Kh. M. Alimardanov
    O. A. Sadygov
    N. I. Garibov
    M. Ya. Abdullaeva
    Russian Journal of Organic Chemistry, 2012, 48 : 1302 - 1308
  • [25] LIQUID-PHASE HYDROGENATION OF ACROLEIN TO ALLYL ALCOHOL ON SUPPORTED COBALT CATALYSTS
    NITTA, Y
    KATO, T
    IMANAKA, T
    HETEROGENEOUS CATALYSIS AND FINE CHEMICALS III, 1993, 78 : 83 - 90
  • [26] THE CONTRIBUTION OF HYDROGEN-PEROXIDE TO ATMOSPHERIC LIQUID-PHASE CHEMISTRY
    KLOCKOW, D
    JACOB, P
    BAMBAUER, A
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 191 : 120 - PETR
  • [27] Optimisation of the technological parameters of epoxidation of allyl alcohol with hydrogen peroxide over Ti-Beta catalyst
    Wroblewska, A
    Rzepkowska, M
    Milchert, E
    OXIDATION COMMUNICATIONS, 2004, 27 (03): : 595 - 609
  • [28] The Ti-MWW catalyst - its characteristic and catalytic properties in the epoxidation of allyl alcohol by hydrogen peroxide
    Wroblewska, Agnieszka
    Fajdek, Anna
    Milchert, Eugeniusz
    Grzmil, Barbara
    POLISH JOURNAL OF CHEMICAL TECHNOLOGY, 2010, 12 (01) : 29 - 34
  • [29] Regeneration of the Ti-SBA-15 Catalyst Used in the Process of Allyl Alcohol Epoxidation with Hydrogen Peroxide
    Wroblewska, A.
    Makuch, E.
    JOURNAL OF ADVANCED OXIDATION TECHNOLOGIES, 2014, 17 (01) : 44 - 52
  • [30] Optimization of the technological parameters of epoxidation of allyl alcohol by hydrogen peroxide over Ti-BETA catalyst
    Wróblewska, A
    Rzepkowska, M
    Milchert, E
    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2004, 79 (04) : 343 - 353