High-performance ITO-free electrochromic films based on bi-functional stacked WO3/Ag/WO3 structures

被引:63
|
作者
Li, Hailing [1 ,2 ]
Lv, Ying [1 ]
Zhang, Xin [3 ]
Wang, Xiaoyi [3 ]
Liu, Xingyuan [1 ]
机构
[1] Chinese Acad Sci, State Key Lab Luminescence & Applicat, Changchun Inst Opt Fine Mech & Phys, Changchun 130033, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Chinese Acad Sci, Key Lab Opt Syst Adv Mfg Technol, Changchun 130033, Peoples R China
基金
美国国家科学基金会;
关键词
Electrochromism; WO3/Ag/WO3; Transparent conductor; Dielectric-metal-dielectric; TRANSPARENT; ELECTRODES; METAL;
D O I
10.1016/j.solmat.2015.01.002
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Stacked WO3/Ag/WO3 (WAW) films were employed as both transparent electrodes and electrochromic materials. These nontoxic, low-cost WAW films that were prepared at room temperature exhibited not only low sheet resistance (12.2 Omega/rectangle) and high transmittance ( > 80%) but also compelling electrochromic performance with high optical contrast (53%) at 650 am, long-term cycling stability (3000 cycles), and short switching time (coloration time = 11 s; bleaching time = 10.5 s). The coloration efficiency of the WAW films was 136 cm(2) C-1, which is higher than those of most electrochromic transition metal oxides. In addition, by utilizing such bi-functional films, the flexible electrochromic film with acceptable performance was obtained. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:86 / 91
页数:6
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